STUDY ON CRYSTALLIZATION BEHAVIOR OF ALL PARA-POLY(ARYL ETHER SULFONE ETHER KETONE KETONE)

WEN Hongli; ZHAN Yulin; LI Jing; ZHONG Ming; SONG Caisheng

doi:10.3724/SP.J.1105.2009.00007

您当前的位置：

首页 >

文章列表页 >

STUDY ON CRYSTALLIZATION BEHAVIOR OF ALL PARA-POLY(ARYL ETHER SULFONE ETHER KETONE KETONE)

Research Article | 更新时间：2021-03-19

- STUDY ON CRYSTALLIZATION BEHAVIOR OF ALL PARA-POLY(ARYL ETHER SULFONE ETHER KETONE KETONE)
- Acta Polymerica Sinica Issue 1, Pages: 7-10(2009)
- 作者机构：
- 作者简介：
- 基金信息：
- DOI：10.3724/SP.J.1105.2009.00007
  CLC：
- Published：20 January 2009，
扫描看全文
WEN Hongli, ZHAN Yulin, LI Jing, ZHONG Ming, SONG Caisheng. STUDY ON CRYSTALLIZATION BEHAVIOR OF ALL PARA-POLY(ARYL ETHER SULFONE ETHER KETONE KETONE). [J]. Acta Polymerica Sinica (1):7-10(2009)
DOI：

WEN Hongli, ZHAN Yulin, LI Jing, ZHONG Ming, SONG Caisheng. STUDY ON CRYSTALLIZATION BEHAVIOR OF ALL PARA-POLY(ARYL ETHER SULFONE ETHER KETONE KETONE). [J]. Acta Polymerica Sinica (1):7-10(2009) DOI： 10.3724/SP.J.1105.2009.00007.

摘要

以AlCl3/DCE/DMF为溶剂体系

采用低温溶液缩聚合成全对位聚醚砜醚酮酮(p-PESEKK)树脂

研究了端基、分子量及溶剂体系对树脂的溶剂诱导结晶行为的影响.结果表明

在AlCl3/DCE/DMF的良溶剂中制得的 p-PESEKK为低结晶度聚合物，由于分子链中四面体结构砜基的影响，树脂熔融后很难再结晶；随脂肪链端基碳原子数的增加

溶剂诱导结晶速度逐渐下降

结晶度降低

与主链结构相同的端基更有利于结晶的形成；高分子量的 p-PESEKK端基的比例相对较小

有利于溶剂诱导结晶.

Abstract

Para-poly(aryl ether sulfone ether ketone ketones) (p-PESEKKs)

were prepared by low temperature solution polycondensation of 4

4′-bis(phenoxy)diphenyl sulfone (DPODPS) and terephthaloyl chloride (TPC) in AlCl3/DCE/DMF solvent system.The effects of some factors on solvent induced crystallization behavior of p-PESEKKs were investigated and compared.The results showed that p-PESEKKs of low crystallinity were obtained in the AlCl3/DCE/DMF good solvent system

and they became amorphous after fusion because of the influence of tetrahedral cofiguration of sulfuryl.It was found that the solvent induced crystallization rate and degree of crystallinity decreased with increasing the carbon number of ester end groups

and the end groups with the same structure as the main chain were favorable for crystallization.The high molecular weight p-PESEKKs with lower proportion of end groups were easy to be crystallized by solvent inducement.

关键词

聚芳醚砜醚酮酮端基结晶溶剂诱导结晶

Keywords

references

更多指标>

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

INFLUENCE OF END GROUP ON THE BANDED STRUCTURE OF PLLA SPHERULITES

THERMAL AGEING BEHAVIOR OF POLY(p-PHENYLENE TEREPHTHALAMIDE) FIBER

MULTISCALE MODELING AND SIMULATION OF POLYMER CRYSTALLIZATION IN COOLING STAGE

STUDIES ON THE CRYSTAL STRUCTURE OF POLYPROPYLENE OBTAINED BY COOLING MELT NEAR MELTING POINT UNDER SHEAR FLOW

CRYSTALLIZATION AND PHASE MORPHOLOGY OF PP/PMMA/PP-g-MAH BLENDS

Related Author

No data

Related Institution

Institution of Chemistry and Chemical Engineering Sciences,Jiangxi Normal University

江西师范大学化学化工学院

Postal code：100190
Tel：010-62588927 Email：gfzxb@iccas.ac.cn
Technical support is provided by Beijing Founder electronics co., LTD 京ICP备05002797号-8 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰