TANG Haiou, DING Yunsheng, LI Boxuan. THE INFLUENCE OF Br[C14im](CH2)4[C14im]Br ON THE STRUCTURE AND PROPERTIES OF PP. [J]. Acta Polymerica Sinica (2):191-194(2009)
DOI:
TANG Haiou, DING Yunsheng, LI Boxuan. THE INFLUENCE OF Br[C14im](CH2)4[C14im]Br ON THE STRUCTURE AND PROPERTIES OF PP. [J]. Acta Polymerica Sinica (2):191-194(2009) DOI: 10.3724/SP.J.1105.2009.00191.
THE INFLUENCE OF Br[C14im](CH2)4[C14im]Br ON THE STRUCTURE AND PROPERTIES OF PP
4-bis(3-tetradecylimidiazolium-1-yl)butane bromide (Br[C14im](CH2)4[C14im]Br) blends were prepared via melting blending
and then the structure and properties of the blend were characterised and tested.Results of testing indicate that Br[C14im](CH2)4[C14im]Br could have a heterogeneous nucleating effect in the PP matrix.Moreover
PP was readily to form α crystal in the PP crystallizing process with the help of Br[C14im](CH2)4[C14im]Br.XRD data show the crystallizing process of PP could be affected by Br[C14im](CH2)4[C14im]Br
and thus decreased the crystallinity of PP.DSC results show the melting point and the crystallization temperature of PP/Br[C14im](CH2)4[C14im]Br blends was close to that of neat PP
this maybe due to the good compatibility of PP to Br[C14im](CH2)4[C14im]Br with long alkyl chains.In addition
the presence of Br[C14im](CH2)4[C14im]Br could improve the antistatic properties of PP apparently
and the surface resistivity of the PP was decreased to 8.97×109 Ω cm when the content of Br[C14im](CH2)4[C14im]Br in the blends was about 3 phr.As for the mechanical properties
the tensile strength decreased while the impact strength of materials presented the opposite results with Br[C14im](CH2)4[C14im]Br incorporated into it.DMA results show the glass transition (Tg) of PP also decreases when 3 phr Br[C14im](CH2)4[C14im]Br exists in its matrix.Therefore
Br[C14im](CH2)4[C14im]Br has the plasticized effect on the PP matrix in our experiments.