WANG Junjun, YU Chongqing, ZHANG Linxi. EFFECT OF NANOPARTICLES ON MORPHOLOGY OF DIBLOCK COPOLYMER FILMS. [J]. Acta Polymerica Sinica (6):530-534(2009)
DOI:
WANG Junjun, YU Chongqing, ZHANG Linxi. EFFECT OF NANOPARTICLES ON MORPHOLOGY OF DIBLOCK COPOLYMER FILMS. [J]. Acta Polymerica Sinica (6):530-534(2009) DOI: 10.3724/SP.J.1105.2009.00530.
EFFECT OF NANOPARTICLES ON MORPHOLOGY OF DIBLOCK COPOLYMER FILMS
Monte Carlo method with annealing method was applied to study the diblock copolymer (A10B6) confined thin films with different volumes of nanoparticles.When the volume of nanoparticles increases
the morphology of diblock copolymer films changes from lamellaes to the mixture of lamellae and cylinder
and finally form the cylinders.Nanoparticles localized within one copolymer block phase.When the volume of nanoparticles are large enough
the 5-
6- and 7-fold cylinder morphologies are formed
and the percentage of 6-fold cylinder are the largest one.The average size of cylinders decreases with increasing the volume of nanoparticles.At the meantime
the average size of copolymers increases first
and then decreases when the volume of nanoparticles increases.This investigation can help us to understand the self-assemble of diblock copolymers with confinements.Some comparisons with experiments results are given.
SYNTHESIS AND CHARACTERIZATION OF POLYPYRROLE NANOPARTICLES VIA UNSTIRRED POLYMERIZATION
TIME AND TEMPERATURE DEPENDENCE OF PHASE-SEPARATION BEHAVIOR FOR POLY(N-METHYL METHACRYLIMIDE)/POLY(VINYLIDENCE FLUORIDE) BLENDS
SYNTHESIS AND CHARACTERIZATION OF POLY(PHTHALAZINONE ETHER NITRILE)POLYDIMETHYLSILOXANE BLOCK COPOLYMERS
DIFFERENT INFLUENCES OF SOLVENTS ON PVDF CASTING SOLUTION PHASE INVERSION AND MEMBRANE SKIN-SUBLAYER STRUCTURE
STUDY ON LIQUIDLIQUID PHASESEPARATION AND ITS EFFECT ON THE CRYSTALLIZATION KINETICS OF BLENDS COMPOSED OF ISOTACTIC POLYPROPYLENE/ETHYLENEPROPYLENE RUBBER