DU Miao, FU Huakang, ZHENG Qiang. RELATIONSHIP BETWEEN ELECTRICAL CONDUCTIVE AND RHEOLOGICAL PERCOLATIONS FOR FIBRES/HDPE COMPOSITES. [J]. Acta Polymerica Sinica (8):756-762(2009)
DOI:
DU Miao, FU Huakang, ZHENG Qiang. RELATIONSHIP BETWEEN ELECTRICAL CONDUCTIVE AND RHEOLOGICAL PERCOLATIONS FOR FIBRES/HDPE COMPOSITES. [J]. Acta Polymerica Sinica (8):756-762(2009) DOI: 10.3724/SP.J.1105.2009.00756.
RELATIONSHIP BETWEEN ELECTRICAL CONDUCTIVE AND RHEOLOGICAL PERCOLATIONS FOR FIBRES/HDPE COMPOSITES
The linear viscoelastic behavior and electrical conductivity of highdensity polyethylene (HDPE) filled with stainless steel fibers (SSF) were investigated and compared with those of carbon black (CB) filled HDPE composites system.It is found that CB/HDPE composites show two electrical conductivity percolation values (φc1 and φc2) and a wide percolation range.However
SSF/HDPE composites present an extremely low threshold of the electrical conductivity percolation (only 0.3 vol%) and a narrow percolation range.Only one conductivity percolation value (φc) was observed.The speciality of conductivity percolation behavior of SSF/HDPE composites owes to the formation of conducting channels of SSF/HDPE composites.It is well recognized that the rheological percolation threshold is identical to the percolation threshold of electrical conductivity for CB/HDPE composites.Whereas
for SSF/HDPE composites
dynamics storage modulus (G′) becomes almost independent of frequency in the low frequency region as the SSF loading increases up to 4.8 vol%
suggesting an onset of solidlike behavior in SSF/HDPE composites.By plotting G′ versus SSF loading
the rheological threshold is determined as 4.8 vol%
which is much lower than the percolation threshold of electrical conductivity
i.e. 0.3 vol%.Additionally
the positive temperature coefficient (PTC) effect was measured for SSF/HDPE and CB/HDPE composites.It reveals that the conductivity channels formed by SSF show a higher stability than those formed by CB particles in HDPE matrix.The difference in the percolation threshold and the stability of conductivity channels are understood in terms of the larger L/D of SSF and the particular conductive mechanism of SSF/HDPE composites.