WANG Suhao, LI Mei, SU Bin, LU Qinghua. PREPARATION AND PROPERTIES OF SUPERHYDROPHOBIC POLYPHENYLENE SULFIDE COMPOSITE COATINGS. [J]. Acta Polymerica Sinica (4):449-455(2010)
DOI:
WANG Suhao, LI Mei, SU Bin, LU Qinghua. PREPARATION AND PROPERTIES OF SUPERHYDROPHOBIC POLYPHENYLENE SULFIDE COMPOSITE COATINGS. [J]. Acta Polymerica Sinica (4):449-455(2010) DOI: 10.3724/SP.J.1105.2010.09124.
PREPARATION AND PROPERTIES OF SUPERHYDROPHOBIC POLYPHENYLENE SULFIDE COMPOSITE COATINGS
A simple spray approach to fabricate superhydrophobic coatings on tile and glass substrates is presented.Commercial available polyphenylene sulfide (PPS) and hydrophobic silica (H—SiO2) powder were suspended in ethanol and the mixed suspensions were spray on substrates.After dried at different temperatures
surface coatings with different hydrophobicity were obtained.By observing the surface morphologies with scanning electron microscope (SEM) and atomic force microscope (AFM)
and measuring water contact angles with a contact angle system
factors affecting the morphology
roughness and contact angle of the surface coatings
such as thermal treatment temperature and the weight ratio of H—SiO2 to PPS
were investigated in detail.With the increase of the thermal treatment temperature
both the surface roughness and the contact angle increased when the temperature was lower than 280℃.As the weight ratio of H—SiO2 to PPS rose from 1∶10 to 1∶1
more H—SiO2 powders accumulated on the surface
leading to a significant increase of hydrophobicity.The surface coating obtained at 280℃ with the weight ratio of H—SiO2 to PPS 1∶1 showed a water contact angle higher than 150° and a sliding angle lower than 4°
exhibiting fascinating superhydrophobic properties.The surface coating could remain superhydrophobicity upon a further increase in thermal treatment temperature or the amount of H—SiO2 powder.Moreover
the surface coatings showed high contact angles
larger than 150°
for all the solutions with pH ranging from 1 to 14. The abrasion resistant property of the asprepared superhydrophobic surface coating was tested using a homemade setup.Being scraped by freely-falling sands
the superhydrophobic coating could keep its high hydrophobicity
while a commercial hydrophobic coating transformed from hydrophobicity to hydrophilicity.This result implied our superhydrophobic surface coating was very stable.Moreover
chalk powders on the superhydrophobic surface coatings could easily be washed off with water
indicating good self-cleaning properties.The presented approach is convenient and can be potentially applied in fabrication of superhydrophobic surfaces in large scale.