XU Hui, LI Jianfeng, ZHANG Hongdong, YANG Yuliang. MICRO PHASE SEPARATION OF DIBLOCK COPOLYMER IN A CLOSED SPHERICAL SHELL. [J]. Acta Polymerica Sinica (5):548-553(2011)
DOI:
XU Hui, LI Jianfeng, ZHANG Hongdong, YANG Yuliang. MICRO PHASE SEPARATION OF DIBLOCK COPOLYMER IN A CLOSED SPHERICAL SHELL. [J]. Acta Polymerica Sinica (5):548-553(2011) DOI: 10.3724/SP.J.1105.2011.10129.
MICRO PHASE SEPARATION OF DIBLOCK COPOLYMER IN A CLOSED SPHERICAL SHELL
By using dynamical method based on the TDGL (time dependent GinzburgLandau) equation with the rebuilded LaplaceBeltrami operator in a spherical shell
the phase behaviors of linear AB diblock copolymer melt confined in the closed spherical shells have been studied.Our approach has focused on the effects of the shells' radius and thickness on the morphology.By analyzing the microscopic phase patterns and the distribution of the components in the shells
we found that with the increasing of the radius and the thickness of the spherical shell
the confinement that polymer chains suffered was reduced and the macroscopic order of morphologies was gradually lost.Especially with the variation of shell thickness
the significant changes of component distribution of two asymmetric blocks within the shell were observed.