RESEARCH PROGRESS OF GEL POLYMER ELECTROLYTES FOR LITHIUM ION BATTERIES. [J]. Acta Polymerica Sinica (2):125-131(2011)
DOI:
RESEARCH PROGRESS OF GEL POLYMER ELECTROLYTES FOR LITHIUM ION BATTERIES. [J]. Acta Polymerica Sinica (2):125-131(2011) DOI: 10.3724/SP.J.1105.2011.10229.
RESEARCH PROGRESS OF GEL POLYMER ELECTROLYTES FOR LITHIUM ION BATTERIES
gel polymer electrolytes (GPEs) have received renewed attention in several areas such as lithium-ion batteries
solar cells and super capacitors due to their promising application.GPEs
swollen in a liquid electrolyte becoming plasticized or a gelled polymer electrolyte
have attracted particular attention because they may provide lighter and safer batteries with longer shelf life
leak proof construction and easy fabrication into desired shape and size.However
GPEs still show poor mechanical strength due to the need for impregnation with the liquid electrolytes.This significant drawback of GPEs hinders their practical application.To overcome these problems
in this review
the up-to-date technologies such as composite gel polymer electrolyte (CGPEs) and porous polymer electrolytes (PPEs) based on the gel concept have been summarized.In the CGPEs
the role of a filler in the membrane is to provide surface groups as physical cross-linking centers for the polymer segments
and thus reduce the polymer reorganization tendency which establishes additional conducting pathways on the filler surface.As a result
the nanosized particles not only lead to better ionic conductivity but also interact with the polymer hosts to enhance the mechanical strength.In PGPEs
due to the existence of the porous structure
the lithium ions can migrate not only in gel electrolyte but also in liquid electrolyte stored in the pores
leading to higher ionic conductivity.In addition
the main characteristics of these gel polymer electrolytes were mentioned.Finally
the future directions are also pointed out.
关键词
凝胶聚合物电解质锂离子电池复合凝胶聚合物电解质多孔凝胶聚合物电解质离子电导率
Keywords
Gel polymer electrolyteLithium ion batteriesComposite gel polymer electrolytePorous gel polymer electrolyteIonic conductivity