LIU Jia, DING Zhitian, LIU Zhengying, FENG Jianmin, YANG Wei, YANG Mingbo. EFFECT OF ROLLER RATES AND TEMPERATURES ON THE STRUCTURE OF HDPE STRETCHED MICROPOROUS MEMBRANES AND LAMELLAE. [J]. Acta Polymerica Sinica (11):1278-1283(2011)
DOI:
LIU Jia, DING Zhitian, LIU Zhengying, FENG Jianmin, YANG Wei, YANG Mingbo. EFFECT OF ROLLER RATES AND TEMPERATURES ON THE STRUCTURE OF HDPE STRETCHED MICROPOROUS MEMBRANES AND LAMELLAE. [J]. Acta Polymerica Sinica (11):1278-1283(2011) DOI: 10.3724/SP.J.1105.2011.10328.
EFFECT OF ROLLER RATES AND TEMPERATURES ON THE STRUCTURE OF HDPE STRETCHED MICROPOROUS MEMBRANES AND LAMELLAE
The HDPE microporous membranes were obtained by a melt-extrusion
annealing
cold stretching
hot stretching and heat setting method.The effect of roller rates and roller temperatures on the structure of the lamellae and the HDPE stretched microporous membranes was characterized by dynamic rheology
FTIR
DSC
SEM and other characterization methods.The results show that the molecular weight
molecular weight distribution and the relaxation time of the HDPE resin used in this experiment can meet the requirements of the present processing conditions for obtaining precursor films with arranged lamellar structure of larger lamellar orientation.Under the same roller temperature
the lamellar orientation of the unannealed and annealed precursor films increases
the lamellar thickness decreases
the micropores distribution regions of the microporous membranes increase and the micropores are more uniform with the roller rates increasing.The lamellar structures arrange more regularly when the roller temperature is 90℃ under the same roller rate
it is a perfect roller temperature to prepare large lamellar orientation precursor films for the resin used in this experiment.Under roller temperature of 90℃
the precursor film with the maximal lamellar orientation
the thinnest lamellar thickness and the narrower lamellar thickness distribution can be obtained
and the structures of the micropore and the micropore distribution are more uniform.