LI Liang-Zhao, ZHANG Xiu-Qin, LUO Fa-Liang, ZHAO Ying, WANG Du-Jin. STRUCTURE AND PROPERTIES OF iPP/MODIFIED NANO-CaCO3 COMPOSITES. [J]. Acta Polymerica Sinica (10):1218-1223(2011)
DOI:
LI Liang-Zhao, ZHANG Xiu-Qin, LUO Fa-Liang, ZHAO Ying, WANG Du-Jin. STRUCTURE AND PROPERTIES OF iPP/MODIFIED NANO-CaCO3 COMPOSITES. [J]. Acta Polymerica Sinica (10):1218-1223(2011) DOI: 10.3724/SP.J.1105.2011.10334.
STRUCTURE AND PROPERTIES OF iPP/MODIFIED NANO-CaCO3 COMPOSITES
Calcium stearate modified nano-CaCO3 (CaSt-nano-CaCO3) was prepared
and iPP /calcium stearate modified nano-CaCO3 (iPP/CaSt-nano-CaCO3) was prepared by melt blending iPP with CaSt-nano-CaCO3 particles.Compared with pure iPP
the addition of CaSt-nano-CaCO3and nano-CaCO3particles both increased flexural strength and flexural modulus of iPP
and impact strength was also improved in these two series composites.In comparison with iPP/nano-CaCO3
the impact toughness of iPP/CaSt-nano-CaCO3composites was improved slightly
while the flexural modulus of iPP/CaSt-nano-CaCO3was obviously increased.Differential scanning calorimetry (DSC) and polarized optical microscopy (POM) tests showed that with increasing CaSt-nano-CaCO3content
the crystallization temperature and the nucleating ability of the composites were all increased.The crystallization temperature of iPP/CaSt-nano-CaCO3is lower than that of iPP/nano-CaCO3 with the same filler content
indicating that the nucleating ability of CaSt-nano-CaCO3is weaker than that of nano-CaCO3 in iPP matrix.Wide-angle X-ray diffraction (WAXD) results showed the composites did not exhibit crystal form after addition of nano-CaCO3and CaSt-nano-CaCO3 particles.Compared with iPP/nano-CaCO3
the presence of calcium stearate increases the melt flow rate (MFR) of iPP composite with the same filler content
implying that the processability of the composites will be improved with the modification of nano-CaCO3 with calcium stearate.
INVESTIGATION ON INTERFACIAL INTERACTION IN NANO-CaCO3/ COMPATIBILIZER/POLYPROPYLENE COMPOSITES
Related Author
No data
Related Institution
1 Key Laboratory for Polymeric Composite and Functional Materials of Ministry of Education,Key Laboratoryof Designed Synthesis and Application of Polymer Materials of Guangdong Province,Materials Science Institute,School of Chemistry and Chemical Engineering,Yat-sen University Guangzhou