RAPID EMUISION POLYMERIZATION OF POLY(2,3-DIMETHYLANILINE) INITIATED BY APS/Fe2+ COMPOSITE OXIDANTS AND ITS PERFORMANCES

Li Ma; Shu-juan Wei; Meng-yun Gan; Fei-fei Chen; Nan Tian; Jun Zeng

doi:10.3724/SP.J.1105.2013.12337

您当前的位置：

首页 >

文章列表页 >

RAPID EMUISION POLYMERIZATION OF POLY(2,3-DIMETHYLANILINE) INITIATED BY APS/Fe2+ COMPOSITE OXIDANTS AND ITS PERFORMANCES

Research Article | 更新时间：2021-03-19

- RAPID EMUISION POLYMERIZATION OF POLY(2,3-DIMETHYLANILINE) INITIATED BY APS/Fe2+ COMPOSITE OXIDANTS AND ITS PERFORMANCES
- Acta Polymerica Sinica Issue 8, Pages: 1033-1038(2013)
- 作者机构：
  
  重庆大学化学化工学院,重庆,400044
- 作者简介：
- 基金信息：
- DOI：10.3724/SP.J.1105.2013.12337
  CLC：
- Published：20 August 2013，
扫描看全文
Li Ma, Shu-juan Wei, Meng-yun Gan, Fei-fei Chen, Nan Tian, Jun Zeng. RAPID EMUISION POLYMERIZATION OF POLY(2,3-DIMETHYLANILINE) INITIATED BY APS/Fe2+ COMPOSITE OXIDANTS AND ITS PERFORMANCES. [J]. Acta Polymerica Sinica (8):1033-1038(2013)
DOI：

Li Ma, Shu-juan Wei, Meng-yun Gan, Fei-fei Chen, Nan Tian, Jun Zeng. RAPID EMUISION POLYMERIZATION OF POLY(2,3-DIMETHYLANILINE) INITIATED BY APS/Fe2+ COMPOSITE OXIDANTS AND ITS PERFORMANCES. [J]. Acta Polymerica Sinica (8):1033-1038(2013) DOI： 10.3724/SP.J.1105.2013.12337.

摘要

采用乳液法

以过硫酸铵 (APS) 和硫酸亚铁 (FeSO4) 为复合氧化剂 (COD)

快速引发合成聚2

3-二甲基苯胺 (P(2

3-DMA)). 通过开路电位 (OCP)、循环伏安 (CV) 和塔菲尔 (Tafel) 测试

探讨了Fe2+对2

3-DMA 聚合速率的影响

优化了 APS/Fe2+ 摩尔比 (n(APS)/n(Fe2+)) 及COD 用量. 通过红外光谱 (FTIR) 和 X-射线衍射 (XRD) 对比分析

印证了 P(2

3-DMA) 电化学性能的表征结果. 结果显示

APS/Fe2+复合氧化剂引发合成的 P(2

3-DMA)

其 FTIR 的主要特征峰发生了红移

表明所得产物的结构更加完整

电子离域程度更大;当 n(APS)/n(Fe2+) 为10∶1

n(COD)/n(2

3-DMA) 为3∶1时

产物的各项性能达到最佳;开路电位显示

Fe2+ 的加入使得 2

3-DMA 的聚合速率得到显著提高

采用复合氧化剂 APS/Fe2+ 制备 P(2

3-DMA) 的产率增大

电化学性能和结晶性更佳.

Abstract

Poly(2

3-dimethylaniline)(P(2

3-DMA)) was synthesized by a rapid emulsion polymerization using ammonium peroxydisulfate and ferrous ion (APS/Fe2+) as composite oxidants.The effect of Fe2+ on the rate of polymerization of 2

3-dimethylaniline (2

3-DMA) was discussed by open circuit potential (OCP) curves

and the molar ratio of APS and Fe2+ and the amount of composite oxidant were optimized by cyclic voltammetry and Tafel curves.And the characterization results of electrochemical properties of P(2

3-DMA) were proved by contrast analysis of infrared spectroscopy (FTIR) and X-ray diffraction (XRD).The experimental results showed that main infrared absorption peaks of P(2

3-DMA) which was synthesized by the composite oxidant exhibited red-shift.The phenomenon revealed that the structure of products was relatively complete and the electron delocalization increased.The optimal properties of P(2

3-DMA) were achieved when the molar ratio of APS to Fe2+ was 10∶1

the molar ratio of APS to 2

3-DMA was 3∶1.The open-circuit potential measurements indicated that the rate of polymerization of 2

3-DMA with the aid of Fe2+ had a substantial increase.The P(2

3-DMA) with higher yield

better electrochemical and crystal properties have been prepared by composite oxidant APS/Fe2+.

关键词

聚23-二甲基苯胺乳液聚合复合氧化剂快速引发

Keywords

Poly(23-dimethylaniline)Emulsion polymerizationComposite oxidantRapid polymerization

references

更多指标>

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Synthesis of Self-demulsification Thermosensitive Polymeric Surfactants and Their Application in Emulsion Polymerization

Studies on the Radical Emulsion Polymerization of Styrene in the Presence of Chain Transfer Monomer

PREPARATION AND PROPERTIES OF A NEW POLYMERIZABLE ANTHRAQUINONE DYE AND ITS COVALENTLY COLORED POLYMER LATEX

FABRICATION OF CORE-SHELL POLYMER MICROSPHERES OF P(St-AM) AND THE CORRESPONDING PHOTONIC CRYSTALS FILMS

SYNTHESIS OF AMPHIPHILIC DENDRON-COIL MACROMONOMER AND RHEOLOGICAL PROPERTIES OF ITS ACRYLATE COPOLYMER EMULSION

Related Author

No data

Related Institution

College of Chemical Engineering, Fuzhou University

School of Materials Science and Engineering, Changzhou University

Department of Chemical Engineering and Key Laboratory of Advanced Materials of Ministry of Education of China, Tsinghua University

College of Chemistry and Chemical Engineering, Yan&rsquo

Research Institute of Materials Science, South China University of Technology

Postal code：100190
Tel：010-62588927 Email：gfzxb@iccas.ac.cn
Technical support is provided by Beijing Founder electronics co., LTD 京ICP备05002797号-8 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰