Li Shu-zhong, Zhang Fen-yu, XU Guan-fan. THE TRANSITIONS OF COPOLYMER OF TETRAFLUOROETHYLENE-HEXAFLUOROPROPYLENE[J]. Acta Polymerica Sinica, 1983,(1):61-64.
Li Shu-zhong, Zhang Fen-yu, XU Guan-fan. THE TRANSITIONS OF COPOLYMER OF TETRAFLUOROETHYLENE-HEXAFLUOROPROPYLENE[J]. Acta Polymerica Sinica, 1983,(1):61-64.DOI:
The transitions of copolymer of tetrafluoroethylene-hexafluoropropylene (FEP) were studied by using the dynamic mechanical and dielectric relaxatiOn methods.Three mechanical transition peaks i.e.a.β and γ,were observed over a temperature range from一90℃ to 160℃ for FEP eop olymer.Efleets of HFP content on the transitions were discussed. Similar to mechanical relaxation.there are three transi.tion peaks of a-γ and δ existing between —186 and 150℃ by dielectric method.Ex-perimental data showed that the peaks measured by dynamic mechanical method are consistent with the peaks measured by dielectric method.The meehanism of dielee-tric δ transition is explained in detail.