Zheng Han-min, Ho Guo-ren. INVESTIGATION ON THE CRYSTALLIZATION KINETICS OF POLYPHENYLENE SULFIDE AND ITS CARBON FIBRE COMPOSITES[J]. Acta Polymerica Sinica, 1983,(1):12-18.
Zheng Han-min, Ho Guo-ren. INVESTIGATION ON THE CRYSTALLIZATION KINETICS OF POLYPHENYLENE SULFIDE AND ITS CARBON FIBRE COMPOSITES[J]. Acta Polymerica Sinica, 1983,(1):12-18.DOI:
The crystallization kinetics of poly (phenylene sulfide) (PPS) and its carbon fibre composites were investigated by dilatometry. An appreciable deviation from the Avrami equation was found for PPS-carbon fiber composites. PPS exhibits a moderate crystallization rate
and possesses a low σσ value
packing density coefficient kc
and a low pre-exponential term G0 of the equation of crystallization kinetics
in compare with polymers such as PE
PMO etc. Go has been found to be the chief factor for the crystallization rate of polymers. Those polymers which possess a lower ρa/ρc value will probablly show a higher crystallization rate.