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纸质出版日期:1965-10-20,
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邓澧儒, 谌福特. 聚酰胺-6纤维拉伸特性的温度-速度换算[J]. 高分子学报, 1965,7(5):297-303.
DENG LI-RHU, SHEN Fu-TE. TEMPERATURE-VELOCITY SUPERPOSITION OF THE DRAWING CHARACTERISTICS OF NYLON-6 FIBRE[J]. Acta Polymerica Sinica, 1965,7(5):297-303.
本文研究了拉伸温度、速度、高聚物晶型、低聚体及水分等因素对聚酰胺-6纤维拉伸特性的影响。认为纤维冷拉伸过程是结晶不完善部分——非晶区分子链段的运动;稍高于T_g温度拉伸
非晶区和晶区内不规整部分可能结晶;在更高温度拉伸明显地产生再结晶
其时主要是晶区的链段运动。低聚体的存在增加纤维的吸水量
这种增塑作用使聚酰胺-6纤维的Tg和再结晶温度大大下降。不同晶型对非晶区的制约作用不同因此有不同的拉伸特性。α晶型位能最低
结构稳定制约作用最强
较难拉伸;γ晶型位能较高
结构不稳定
较易拉伸且不易再结晶
生产纤维应当控制这种晶型以利于拉伸。应用时-温换算原理处理拉伸等温线与等速线结果得到总曲线;以T_g为参考温度并选择合理的常数得到W.L.F.方程如下: logαT=-43.3(T-Tg)/(374.8+T-Tg)利用总曲线可以很方便地力生产选择合理的拉伸工艺条件。
The effects of temperature,rate of drawing,crystalline form,and the presence of oli-gomers and water in the polymer on the drawing characteristics of Nylon一6 have been studied.Experimental results indicate that the mechanism of cold drawing of Nylon一6 fibre is in agreement with Lazurkin’s relaxation theory.The authors suggest that cold .drawing(under Tg) of polycrystalline polymer is a relaxation process of chain segments of the noncrystalline region.When the drawing temperature is higher than Tg,crystalli-zation and recrystallization begin,the relaxation process is mainly due to the segmental motion in the crystalline region.Tg and recrystallization temperature of Nylon-6 fibre are greatly reduced by the plasticizing effect of oligomer and water.Since the segmental motion is constrained by the crystalline region,the drawing characteristics of Nylon-6 fibre in a- and γ-forms are different.The effect of constraint of the more stable a-form is greater cban the meta—stable γ-form.ThUS the γ-form of Nylon-6 is favoured for the drawing of fibre.Time-temperature superposition is sucessfully applied to the drawing characteristics of Nylon-6 fibre. and the W.L.F.equation is satisfied:log aT=一43.3(T—Tg)/(374.8+T一Tg) The master curve SO obtained is valuable for the selection of technical conditions of fibre drawing.
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