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纸质出版日期:1965-10-20,
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钱人元, 漆宗能, 吴林生. 晶区分子链构象及拉伸取向对聚酰胺-6分子运动的影响[J]. 高分子学报, 1965,7(5):291-296.
CHIEN JEN-YUAN, CHI TSUNG-NAN, WU LIN-SEN. EFFECTS OF UNIAXIAL ORIENTATION AND MOLECULAR CONFORMATION ON THE MOLECULAR MOTIONS OF NYLON-6[J]. Acta Polymerica Sinica, 1965,7(5):291-296.
用声频共振法在-150°—170℃范围内测定了晶区构象为α、γ、γ+α型以及经不同拉体程度的聚酰胺-6单纤维的动态力学性质的温度谱。除三个已知的内耗峯—— -110℃(βa)
-40℃(β’a)
50℃(αa)以外
对晶区为γ构象且含有单体及低聚体的聚酰胶-6观察到一个新的内耗峯
130℃(α’a)。具有α构象的试样
其αa内耗峯出现的温度较具有γ构象的试样为高。 经碘处理而未脱碘的聚酰胺-6
(β’a)内耗峯高度显著增加
进一步证实β’a内耗峯与自由酰胺基的运动有关。β’a内耗峯的高度亦随拉伸比的增加而增高
说明在拉伸过程中
酰胺基之间的氢键有破坏的可能性。 出现在130℃处的α’c内耗峯随拉伸比的增加其高度显著地下降
当拉伸到3.8倍时不再出现α’c内耗峯。结合晶区分子链构象及碘处理对α’c内耗峯的影响
我们认力α’c内耗峯应为γ构象部分的松弛运动。
The temperature spectra of the dynamic mechanical properties of Nylon-6 monofila-ments of different draw ratios and with α,γ and γ+α forms of chain conformation in the crystalline region,were determined over a temperature range extending from一150°to + 170℃ by using the resonanting reed method in audio frequencies.In addition to the three internal friction peaks known in the literature,i.e. 一110℃(βα),一40℃(β'α) and 50℃(αα),a new loss peak at 130℃ was observed for Nylon-6 in γ-form containing monomer and oligomers.According tO the experimental results,the temperature of α-peak for samples in α-form is higher than those in γ-form,that means that chain segments in the γ-form have higher mobility than those in the a-form.The loss peak β'α was greatly enhanced when iodine was absorbed in the fibre.This supports the view that the β'α peak is connected with the motion of chain segments containing free amide groups.The β'α-peak also grows rapidly with orientation,indicating the possible breaking up of hydrogen bonds during the stret-ching process.The new internal friction peak ac was found in γ-forms only.The peak height decreased rapidly with increasing draw ratio and vanished at a draw ratio of 3.8. Experi-mental results indicate that the ac 1088 peak is due to molecular motions of the segments in the crystalline region in γ—conformation.
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