含胺基功能性单体的聚合研究——Ⅶ.N-(4-N′,N′-二甲氨基苯基)代丙烯酰胺作为氧化还原引发体系组分的研究

李福绵; 王林; 冯新德

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含胺基功能性单体的聚合研究——Ⅶ.N-(4-N′,N′-二甲氨基苯基)代丙烯酰胺作为氧化还原引发体系组分的研究

研究简报 | 更新时间：2021-03-19

- 含胺基功能性单体的聚合研究——Ⅶ.N-(4-N′,N′-二甲氨基苯基)代丙烯酰胺作为氧化还原引发体系组分的研究
- STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO-GROUPSⅦ. STUDY ON THE USE OF N-(4-N', N'-DIMETHYLAMINOPHENYL). SUBSTITUTED ACRYLAMIDES AS COMPONENT OF REDOX INITIATOR SYSTEM
- 高分子学报 1984年第3期页码：237-240
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- 纸质出版日期：1984-6-20，
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李福绵, 王林, 冯新德. 含胺基功能性单体的聚合研究——Ⅶ.N-(4-N′,N′-二甲氨基苯基)代丙烯酰胺作为氧化还原引发体系组分的研究[J]. 高分子学报, 1984,(3):237-240.

LI Fu-mian, WANG Lin, FENG Xin-de. STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO-GROUPSⅦ. STUDY ON THE USE OF N-(4-N', N'-DIMETHYLAMINOPHENYL). SUBSTITUTED ACRYLAMIDES AS COMPONENT OF REDOX INITIATOR SYSTEM[J]. Acta Polymerica Sinica, 1984,(3):237-240.
李福绵, 王林, 冯新德. 含胺基功能性单体的聚合研究——Ⅶ.N-(4-N′,N′-二甲氨基苯基)代丙烯酰胺作为氧化还原引发体系组分的研究[J]. 高分子学报, 1984,(3):237-240. DOI：

LI Fu-mian, WANG Lin, FENG Xin-de. STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO-GROUPSⅦ. STUDY ON THE USE OF N-(4-N', N'-DIMETHYLAMINOPHENYL). SUBSTITUTED ACRYLAMIDES AS COMPONENT OF REDOX INITIATOR SYSTEM[J]. Acta Polymerica Sinica, 1984,(3):237-240. DOI：

摘要

Abstract

The kinetics of the polymerization of methyl methacrylate (MMA) initiated with initiator system of benzoyl peroxide (BPO) combined with N-(4-N'

N'-dimethylaminophenyl) acrylamide (DMAPAA) or N-(4N' N'-dimettylaminophenyl) methacrylamide .(DMAPMA) have been investigated. The rate equations are given asRp = Kp

[DMAPAA]1/2[BPO]1/2[MMA] and Rp = Kp [ DMAPMA]1/2 [ BPO ]1/2[ MMA]

respectively. The overall activation energies of these polymerization were determined as low as 8.4 and 7.2 kcal/mol

respectively. The monomers containing teritiary amino groups not only initate the polymerization by redox nature

but also incorporate into the polymer chains.

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