聚壬酰胺的制备纺丝及结构与性能测定

王葆仁; 王有槐; 王幼雄

doi:null

您当前的位置：

首页 >

文章列表页 >

聚壬酰胺的制备纺丝及结构与性能测定

研究论文 | 更新时间：2021-03-19

- 聚壬酰胺的制备纺丝及结构与性能测定
- THE PREPARATION AND SPINNING OF POLYPELARGON-AMIDE AND THE STUDIES OF STRUCTURE AND PROPERTIES
- 高分子学报 1984年第1期页码：27-32
- 作者机构：
- 作者简介：
- 基金信息：
- DOI：
  中图分类号：
- 纸质出版日期：1984-2-20，
扫描看全文
王葆仁, 王有槐, 王幼雄. 聚壬酰胺的制备纺丝及结构与性能测定[J]. 高分子学报, 1984,(1):27-32.

Wang Bao-ren, WANG Yu-huai, Wang You-xiong. THE PREPARATION AND SPINNING OF POLYPELARGON-AMIDE AND THE STUDIES OF STRUCTURE AND PROPERTIES[J]. Acta Polymerica Sinica, 1984,(1):27-32.
王葆仁, 王有槐, 王幼雄. 聚壬酰胺的制备纺丝及结构与性能测定[J]. 高分子学报, 1984,(1):27-32. DOI：

Wang Bao-ren, WANG Yu-huai, Wang You-xiong. THE PREPARATION AND SPINNING OF POLYPELARGON-AMIDE AND THE STUDIES OF STRUCTURE AND PROPERTIES[J]. Acta Polymerica Sinica, 1984,(1):27-32. DOI：

摘要

9-氨基壬酸系从癸二酸经单酯化、氨化和Hofmann重排制得。该单体以10克规模在玻璃管中和以4公斤量在15升聚合釜中

于260℃聚合成聚壬酰胺。聚合物在288℃纺丝

120℃牵伸

得到尼龙-9纤维。测定了聚合物和纤维的结构和多种性能。

Abstract

9-Amino-pelargonic acid was synthesized from sebacic acid through mono-esterification

ammonolysis and Hofmann's degradation. The monomer was polycondensed both in 15 g and in 4 kg scale

by heating at 260℃ for 3-4 hours. The molecular weight of the polymer attained 20000-26000. The polymer was spun into nylon-g fiber at 288℃ and drawn at 120℃ to 4.5 times its length. The structure and the properties of the polymer and the fiber were determined by various methods

which included X-ray diffraction

NMR

dynamic viscoelastioc

DTA

viscous flow

etc. The outstanding features of the nylon-g fiber are its wearbility

double flexural times.

关键词

Keywords

references

更多指标>

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

暂无数据