铁体系催化丁二烯聚合的研究——烷基铁络合物聚合丁二烯

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研究简报 | 更新时间：2021-03-19

- 铁体系催化丁二烯聚合的研究——烷基铁络合物聚合丁二烯
- STUDIES ON THE POLYMERIZATION OF BUTADIENE IN THE PRESENCE OF IRON CATALYST——ALKYL IRON COMPLEXES POLYMERIZED BUTADIENE
- 高分子学报 1984年第2期页码：149-152
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- 纸质出版日期：1984-4-20，
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刘国智, 王凤江. 铁体系催化丁二烯聚合的研究——烷基铁络合物聚合丁二烯[J]. 高分子学报, 1984,(2):149-152.

LIU Gou-zhi, WANG Feng-jiang. STUDIES ON THE POLYMERIZATION OF BUTADIENE IN THE PRESENCE OF IRON CATALYST——ALKYL IRON COMPLEXES POLYMERIZED BUTADIENE[J]. Acta Polymerica Sinica, 1984,(2):149-152.
刘国智, 王凤江. 铁体系催化丁二烯聚合的研究——烷基铁络合物聚合丁二烯[J]. 高分子学报, 1984,(2):149-152. DOI：

LIU Gou-zhi, WANG Feng-jiang. STUDIES ON THE POLYMERIZATION OF BUTADIENE IN THE PRESENCE OF IRON CATALYST——ALKYL IRON COMPLEXES POLYMERIZED BUTADIENE[J]. Acta Polymerica Sinica, 1984,(2):149-152. DOI：

It had been identified by the analysis of the structure that diethyl bis (1

10-phenan-throline) iron Complex was formed by the reaction of ferric acetylacetonate with diethyl aluminium ethoxide in the presence of 1

10-phenanthroline.Butadiene does not polymerize by Et2Fe (phen)2 alone but polymerize when triethyla-luminium is used as co-catalyst

giving a polymer with mid-vinyl structure. Et2pe (dipy)2 can also polymerize butadiene to high polymer in the presence of triethylaluminium.

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