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纸质出版日期:2008-7-20,
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张纯, 于杰, 张凯舟, 何力, 周国治, 李谦. 微孔对HDPE缺口冲击强度及断面形貌特征的影响研究[J]. 高分子学报, 2008,(7):726-732.
ZHANG Chun, YU Jie, ZHANG Kaizhou, He Li, ZHOU Guozhi, LI Qian. EFFECTS OF MICROCELLS ON NOTCHED IMPACT STRENGTH AND FRACTURE SURFACE MORPHOLOGY OF HDPE[J]. Acta Polymerica Sinica, 2008,(7):726-732.
张纯, 于杰, 张凯舟, 何力, 周国治, 李谦. 微孔对HDPE缺口冲击强度及断面形貌特征的影响研究[J]. 高分子学报, 2008,(7):726-732. DOI: 10.3724/SP.J.1105.2008.00726.
ZHANG Chun, YU Jie, ZHANG Kaizhou, He Li, ZHOU Guozhi, LI Qian. EFFECTS OF MICROCELLS ON NOTCHED IMPACT STRENGTH AND FRACTURE SURFACE MORPHOLOGY OF HDPE[J]. Acta Polymerica Sinica, 2008,(7):726-732. DOI: 10.3724/SP.J.1105.2008.00726.
在-196℃~+23℃的温度范围内,系统测试了微孔发泡和未发泡高密聚乙烯(HDPE)的Izod缺口冲击强度,进行了动态粘弹谱(DMA)和冲击断口系统观察分析.根据实验结果,研究了外加冲击力场作用下微发泡高密度聚乙烯变形断裂过程和机理,揭示了微孔的存在导致一定实验温度下的材料变形断裂机制发生了变化,微孔的引入一方面减小了试样(材料)的有效承载面积,另一方面导致HDPE试样芯部基体材料的应力状态改变为平面应力状态,易于在冲击载荷下产生塑性变形或在低温脆断条件下裂纹尖端钝化阻止裂纹扩展,其综合作用的结果导致微孔发泡和未发泡HDPE的Izod缺口冲击强度随实验温度的变化规律存在差异,且实验温度高于-35℃时,微孔发泡HDPE的缺口冲击强度低于未发泡的,实验温度低于-35℃后,微孔发泡HDPE的缺口冲击强度高于未发泡的.
The Izod notched impact strength of foamed and unfoamed high density polyethylene (HDPE) was tested systematically in a wide temperature range from -196℃ to 23℃
and the impact fracture surface morphology of samples was observed and analyzed by scanning electron microscopy (SEM).The size and size distribution of cells were analyzed by using the image_pro plus software.The samples were also characterized by dynamic mechanical measurements.The results show that the cell size is in the range of 35~40 μm having a normal distribution.The Izod notched impact strength of unfoamed HDPE is much higher than that of the foamed ones at room temperature.The impact strength of both samples decreases with the descent of test temperatures.As the decreasing rate of impact strength for unfoamed samples is high than that for the foamed samples
an inversion of impact strength values between the two samples occurs at around -35℃
below which the foamed HDPE samples exhibit higher impact strength than the unfoamed HDPE samples.For both samples a sudden drop of impact strength can be observed in the temperature range from -43℃ to -53℃ followed by a very slow decrease trend in the low temperature range
and the transition between the two regions is quite sharp.The effects of microcells on the impact properties of HDPE were analyzed.It is supposed that the existence of microcells may reduce the actual section area of samples under impact testing
on the other hand it may also favor the plastic deformation of the HDPE matrix and the inhibition of crack propagation under low temperatures.The contribution of these factors determines the different temperature dependence of the foamed and unfoamed HDPE samples under impact testing.
微孔冲击强度断裂微发泡高密度聚乙烯
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