ZHENG Yanyu, HU Binghuan, LIN Jinhuo. INFLUENCE OF URUSHIOLBASED EMULSIFIER ON THE RHEOLOGICALBEHAVIOR OF OIL IN WATER RAW LACQUER EMULSION[J]. Acta Polymerica Sinica, 2008,(9):920-924.
ZHENG Yanyu, HU Binghuan, LIN Jinhuo. INFLUENCE OF URUSHIOLBASED EMULSIFIER ON THE RHEOLOGICALBEHAVIOR OF OIL IN WATER RAW LACQUER EMULSION[J]. Acta Polymerica Sinica, 2008,(9):920-924. DOI: 10.3724/SP.J.1105.2008.00920.
The oil in water (O/W) type raw lacquer emulsion (RLE) was prepared by using a mixed emulsifier of urushiolbased emulsifier (UE)/polyvinyl alcohol (PVA).The effects of concentration of urushiolbased emulsifier UE10 (cUE10)
mixed emulsifier UE10/PVA concentration (cME) and the structure of UE on the rheology of RLE were investigated.The results showed that the viscosity of RLE increased with increasing cUE10
and RLE exhibited shearthinning behavior.At low concentration of mixed emulsifier UE10/PVA(cME≤8.5%)
RLE belonged to pseudoplastic fluids
and shearthinning character was observed.As cME was increased to no less than 9.0%
the viscosity of RLE decreased remarkably with the increasing of shear rate
pass through a minimum
then increased slowly with increasing shear rate
and RLE exhibited swell fluids characteristics.The viscosity of RLE increased with increasing the chain length of oxyethyl groups in UE molecules
and the flow curves of RLE prepared by UE with different chain length of oxyethyl groups were well described by the Hershel-Bulkley equation.Networklike structure between RLE particles became stronger with increasing of chain length of oxyethyl groups in UE molecules.