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纸质出版日期:2009-6-20,
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孙亮, 王珺, 韩平畴. 单根聚己内酯电纺亚微米纤维的动力学特性分析[J]. 高分子学报, 2009,(6):535-539.
SUN Liang, WANG Jun, HAN Ray Peng Siew. A DYNAMIC INVESTIGATION OF THE PROPERTIES OF A SINGLE-STRAND,ELECTROSPUN PCL SUB-MICRO FIBER[J]. Acta Polymerica Sinica, 2009,(6):535-539.
孙亮, 王珺, 韩平畴. 单根聚己内酯电纺亚微米纤维的动力学特性分析[J]. 高分子学报, 2009,(6):535-539. DOI: 10.3724/SP.J.1105.2009.00535.
SUN Liang, WANG Jun, HAN Ray Peng Siew. A DYNAMIC INVESTIGATION OF THE PROPERTIES OF A SINGLE-STRAND,ELECTROSPUN PCL SUB-MICRO FIBER[J]. Acta Polymerica Sinica, 2009,(6):535-539. DOI: 10.3724/SP.J.1105.2009.00535.
通过静电纤维制造技术得到直径范围在100~500 nm的PCL亚微米纤维,并使用信号发生器和压电片联用对收集到的单根纤维进行振动实验,由共振频率数据得到单根纤维的弹性模量,并同时对直径的测量方法进行了修正.实验结果显示,PCL亚微米纤维的弹性模量随直径变化而显著增加,存在明显的尺寸效应.通过引入应变梯度的振动模型对实验中观测到的尺寸效应进行了理论解释,等效弹性模量的理论预测值与实验数据吻合良好.
The polymer micro- or nano- fibers have been rapidly gaining popularity as a construction matrix for tissue engineering scaffolds.This paper presents a dynamic investigation of the poly(ε-caprolactone)(PCL) sub-micro fibers with diameters ranging from 100 nm to 500 nm by electrospinning method.To obtain the dynamic properties
the fiber was placed on a surface which had a groove of 100 μm width
and the experiments using a functional generator and piezo-tablet were conducted on a vibrating single-strand fiber.The amplitude and driving frequency can be observed by using the ultra-high optical microscope and functional generator respectively.Additionally
since the dynamic property is highly sensitive to the fiber diameter
and real fibers have an ellipsoidal cross-section
it is necessary to correct the experimental data.The equal diameter is defined and the value can be measured by using the AFM equipment.The elastic modulus can be obtained when the PCL fiber beam arrived at its first resonant frequency.Our measurements show that its elastic modulus exhibits an inverse size dependency with the fiber diameter.The elastic modulus of the fiber increased obviously when its diameter was reduced past a threshold size.A dynamics-based strain gradient model was presented to correlate with the experimental data
and it appeared to explain the phenomenon quite accurately.
聚合物亚微米纤维尺寸效应动力学实验应变梯度理论
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