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纸质出版日期:2011-4-20,
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帕提曼尼扎木丁, 阿布力孜伊米提. PVA薄膜光波导气敏元件及其应用研究[J]. 高分子学报, 2011,(4):366-370.
PATIMA Nizamidin, ABLIZ Yimit. PVA THIN FILM BASED OPTICAL WAVEGUIDE SENSOR AND ITS APPLICATION IN XYLENE DETECTION[J]. Acta Polymerica Sinica, 2011,(4):366-370.
帕提曼尼扎木丁, 阿布力孜伊米提. PVA薄膜光波导气敏元件及其应用研究[J]. 高分子学报, 2011,(4):366-370. DOI: 10.3724/SP.J.1105.2011.10098.
PATIMA Nizamidin, ABLIZ Yimit. PVA THIN FILM BASED OPTICAL WAVEGUIDE SENSOR AND ITS APPLICATION IN XYLENE DETECTION[J]. Acta Polymerica Sinica, 2011,(4):366-370. DOI: 10.3724/SP.J.1105.2011.10098.
将纯聚乙烯醇(PVA)和掺有维生素C的PVA作为敏感试剂,通过旋转甩涂法分别研制出了PVA薄膜/锡掺杂玻璃光波导元件和VC-PVA薄膜/锡掺杂玻璃光波导元件并检测其气敏特性.实验结果表明,PVA薄膜/锡掺杂玻璃光波导元件对二甲苯气体有良好的选择性响应,其响应浓度范围为10-4~10-7(体积比);加入VC后,使此敏感元件具有更高的灵敏度,更宽的响应范围即Vc-PVA薄膜/锡掺杂玻璃光波导元件对浓度为10-8的二甲苯气体有很明显的响应.这些气敏元件具有灵敏度高、线性响应范围宽、响应恢复速度快、制作工艺简单等特点.
The optical waveguide (OWG) sensor used consists of a substrate
waveguide layer (K+ion exchanged layer or tindiffused OWG) and thin top layer (sensing layer).The semiconductor laser beam (630~680 nm) was introduced into the OWG using a prism coupler (glass prism
n = 1.78; and a matching liquid
diiodomethane
n = 1.74)
and it emerged from another prism coupler.The intensity of the output light was monitored by using a photomultiplier detector
and the output light intensity was recorded by a computer.Pure air that functioned as a carrier and dilution gas flowed through the cell at a constant rate of 40 mL/min in order to transfer the xylene gas to the sensor.All measurements were made at room temperature.Pure PVA and Vc embedded PVA were chosen as sensitive materials
the PVA film/tin-diffused glass OWG and VC-PVA thin film/tin-diffused glass OWG were fabricated by spin- coating methods.We used this two OWG sensors to detect xylene gas
and the experimental result shows that the PVA film/tin-diffused glass OWG exhibited a good response to xylene gas
its detection range was 10-4~10-7.While the Vc-PVA thin film/tin-diffused glass OWG exhibited higher sensitivity and larger response range (this OWG sensor has a considerable response to 10-8 of xylene gas).These sensors were also characterized by high sensitivity
simple structure and were easily fabricated.
光波导气敏元件VC-PVA薄膜二甲苯气敏性
OWG gas sensing elementVCPVA thin filmXyleneGas sensing properties
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