FEI Guo-Xia, LIU Yuan, WANG Qi. SYNTHESIS OF NOVOLAC-BASED CHAR FORMER AND ITS SYNERGISTIC EFFECTS WITH MAGNESIUM HYDROXIDE ON FLAME RETARDANCY OF POLYAMIDE-6[J]. Acta Polymerica Sinica, 2011,(10):1195-1201.
FEI Guo-Xia, LIU Yuan, WANG Qi. SYNTHESIS OF NOVOLAC-BASED CHAR FORMER AND ITS SYNERGISTIC EFFECTS WITH MAGNESIUM HYDROXIDE ON FLAME RETARDANCY OF POLYAMIDE-6[J]. Acta Polymerica Sinica, 2011,(10):1195-1201. DOI: 10.3724/SP.J.1105.2011.10307.
was designed and successfully synthesized to modify Magnesium hydroxide (MH) flame retardant polyamide-6 (PA6).The synthesized BPF was characterized by FTIR
1H-NMR
XRD and TGA
etc.The experiment results showed that BPF possessed good charring performance
about 61.4 wt% solid residue remained even after heating to 750℃ for MH/BPF/PA6 system.The degraded BPF produced glassy B2O3 covering on the surface of the burning material
and effectively isolated the oxygen from interior material
therefore remarkably enhanced the flame retardancy of the material
reaching UL94-1.6mm V0 rating.BPF also served as an efficient lubricant and greatly improved the processability of the material.In addition
BPF did not deteriorate the mechanical properties of the flame retardant material
showing comprehensive modification effects on MH flame retardant PA6.