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纸质出版日期:2011-10-20,
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李良钊, 张秀芹, 罗发亮, 赵莹, 王笃金. 改性纳米碳酸钙-聚丙烯复合材料的结构与性能研究[J]. 高分子学报, 2011,(10):1218-1223.
LI Liang-Zhao, ZHANG Xiu-Qin, LUO Fa-Liang, ZHAO Ying, WANG Du-Jin. STRUCTURE AND PROPERTIES OF iPP/MODIFIED NANO-CaCO3 COMPOSITES[J]. Acta Polymerica Sinica, 2011,(10):1218-1223.
李良钊, 张秀芹, 罗发亮, 赵莹, 王笃金. 改性纳米碳酸钙-聚丙烯复合材料的结构与性能研究[J]. 高分子学报, 2011,(10):1218-1223. DOI: 10.3724/SP.J.1105.2011.10334.
LI Liang-Zhao, ZHANG Xiu-Qin, LUO Fa-Liang, ZHAO Ying, WANG Du-Jin. STRUCTURE AND PROPERTIES OF iPP/MODIFIED NANO-CaCO3 COMPOSITES[J]. Acta Polymerica Sinica, 2011,(10):1218-1223. DOI: 10.3724/SP.J.1105.2011.10334.
制备了硬脂酸钙包覆的纳米碳酸钙(CaSt-nano-CaCO3)
并采用熔融共混的方法制备出iPP/CaSt-nano-CaCO3和iPP/nano-CaCO3复合材料.与纯iPP相比
复合材料的弯曲强度和弯曲模量随着 CaCO3粒子含量的增加而提高
冲击性能也得到改善.相对于iPP/nano-CaCO3
iPP/CaSt-nano-CaCO3复合材料的冲击强度略有改善
而弯曲强度和弯曲模量明显提高.偏光显微镜和示差扫描量热研究表明
随着CaSt-nano-CaCO3含量增大
复合材料的结晶温度升高
成核性能增大
但其结晶温度低于同等粒子含量的iPP/nano-CaCO3复合材料
即CaSt-nano-CaCO3对iPP结晶的成核作用弱于nano-CaCO3
表明CaSt的引入降低了CaCO3的成核活性.广角X射线衍射试验研究表明引入改性与未改性纳米碳酸钙后复合材料均未出现晶型.熔体流动速率测试表明
相比于iPP/nano-CaCO3
硬脂酸钙的存在改善了复合材料的加工流动性能.
Calcium stearate modified nano-CaCO3 (CaSt-nano-CaCO3) was prepared
and iPP /calcium stearate modified nano-CaCO3 (iPP/CaSt-nano-CaCO3) was prepared by melt blending iPP with CaSt-nano-CaCO3 particles.Compared with pure iPP
the addition of CaSt-nano-CaCO3and nano-CaCO3particles both increased flexural strength and flexural modulus of iPP
and impact strength was also improved in these two series composites.In comparison with iPP/nano-CaCO3
the impact toughness of iPP/CaSt-nano-CaCO3composites was improved slightly
while the flexural modulus of iPP/CaSt-nano-CaCO3was obviously increased.Differential scanning calorimetry (DSC) and polarized optical microscopy (POM) tests showed that with increasing CaSt-nano-CaCO3content
the crystallization temperature and the nucleating ability of the composites were all increased.The crystallization temperature of iPP/CaSt-nano-CaCO3is lower than that of iPP/nano-CaCO3 with the same filler content
indicating that the nucleating ability of CaSt-nano-CaCO3is weaker than that of nano-CaCO3 in iPP matrix.Wide-angle X-ray diffraction (WAXD) results showed the composites did not exhibit crystal form after addition of nano-CaCO3and CaSt-nano-CaCO3 particles.Compared with iPP/nano-CaCO3
the presence of calcium stearate increases the melt flow rate (MFR) of iPP composite with the same filler content
implying that the processability of the composites will be improved with the modification of nano-CaCO3 with calcium stearate.
硬脂酸钙纳米碳酸钙聚丙烯复合材料结晶力学性能
Calcium stearateNano-CaCO3Polypropylene compositesMechanical propertiesCrystallization
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