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南京理工大学化工学院,南京,210094
纸质出版日期:2011-12-20,
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王传宝, 应三九, 肖正刚. 竹纤维改性聚丙烯超临界CO2发泡性能的研究[J]. 高分子学报, 2011,(12):1419-1424.
WANG Chuanbao, YING Sanjiu, XIAO Zhenggang. INVESTIGATION OF PP/BAMBOO FIBER BLEND FOAMS USING SUPERCRITICAL CO2[J]. Acta Polymerica Sinica, 2011,(12):1419-1424.
王传宝, 应三九, 肖正刚. 竹纤维改性聚丙烯超临界CO2发泡性能的研究[J]. 高分子学报, 2011,(12):1419-1424. DOI: 10.3724/SP.J.1105.2011.10368.
WANG Chuanbao, YING Sanjiu, XIAO Zhenggang. INVESTIGATION OF PP/BAMBOO FIBER BLEND FOAMS USING SUPERCRITICAL CO2[J]. Acta Polymerica Sinica, 2011,(12):1419-1424. DOI: 10.3724/SP.J.1105.2011.10368.
为了提高竹纤维的分散性
借鉴打浆造纸法制备得到了已表面处理的竹纤维和聚丙烯纤维的复合材料
并在扫描电镜下对复合材料样品的断面进行了表征.结果表明
打浆造纸法这种工艺很好地解决了竹纤维在聚丙烯中的分散
得到了竹纤维分布均匀的竹纤维/聚丙烯复合材料;并以竹纤维含量为25%的复合材料作为超临界CO2发泡的研究对象
根据异相成核机理通过快速降压法制备得到了竹纤维/聚丙烯发泡材料
并探讨了发泡工艺条件(饱和压力、饱和时间和饱和温度)对泡孔参数的影响.用扫描电镜对发泡样品的泡孔结构进行了表征
结果表明
竹纤维的加入大大改善了聚丙烯的发泡能力
得到了泡孔尺寸均一、分布均匀的竹纤维/聚丙烯发泡材料
泡孔直径最小达到5.24 m时
泡孔密度则达到最大值1.92109 cells/cm3.
In order to solve the problem of the dispersion of bamboo fiber
the preparation of the surface treated bamboo fiber and polypropylene composite was carried out in reference to the way of papermaking.The fracture surface of the composite was characterized by the scanning electron microscope.The result showed: the processes of papermaking method solved the problem of the dispersion of bamboo fiber in the composite
and obtained the uniform bamboo fiber distribution of the bamboo fiber/PP composite materials. The composites which contained 25 wt% bamboo fiber were autoclave-foamed in a batch process in supercritical CO2 according to the heterogeneous nucleation mechanism using supercritical CO2 as physical blowing agents
and the influences of the foam process conditions (such as saturated pressure
saturated time and saturated temperature) on the bubble pore parameters were discussed. Using a scanning microscope
the cell structures of the foaming samples were also investigated
the result indicated: the bamboo fiber had a great positive impact on improving the cell morphology and the cell density.There would be uniform cell size and distribution in the bamboo fiber/PP composite foams.When a minimum bubble diameter was 5.24 m
the cell density reached a maximum
1.92 109 cells/cm3
超临界CO2聚丙烯竹纤维发泡打浆造纸法
Supercritical CO2PPBamboo fiberFoamPapermaking
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