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纸质出版日期:2011-9-20,
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滕超, 薛奇. 高分子链的去拥挤转变及低温流动[J]. 高分子学报, 2011,(9):1001-1006.
TENG Chao, XUE Qi. UNJAMMING TRANSITION AND COLD FLOW OF POLYMER CHAINS[J]. Acta Polymerica Sinica, 2011,(9):1001-1006.
滕超, 薛奇. 高分子链的去拥挤转变及低温流动[J]. 高分子学报, 2011,(9):1001-1006. DOI: 10.3724/SP.J.1105.2011.11123.
TENG Chao, XUE Qi. UNJAMMING TRANSITION AND COLD FLOW OF POLYMER CHAINS[J]. Acta Polymerica Sinica, 2011,(9):1001-1006. DOI: 10.3724/SP.J.1105.2011.11123.
简述了拥挤理论的基本原理
运用拥挤理论来说明高分子链间弱相互作用对高分子链所处的状态的影响
特别是对高分子玻璃化转变的影响.在实验中
采用固体核磁共振方法探测高分子的链间邻近度
并比较了不同链间邻近度的高分子样品在玻璃化转变温度以下的压力诱导流行行为
发现即使测试温度比高分子玻璃化转变温度低132℃
高分子链在压力下依然可以进行局部流动
即高分子链的低温流动行为.拥挤理论为高分子链的低温流动行为提供了依据
并为玻璃化转变的机理提供了新的解释.与此同时
高分子链的低温流动也为高分子加工提供了新的思路和方法.
Jamming occurs when a system develops a yield stress behaves as a solid in a disordered state
and it governs the transition behavior of foams
emulsions
colloidal suspensions
pastes
granular media and molecular glasses.For polymer glasses
when the interchain proximity was enlarged
the weak interaction between polymer chains was decreased
and these loosely packed chains can flow solely by applying pressure at temperature 132 degrees below their calorimetric glass transition temperature
Tg
which means Tg decreased to a great extent in this progress.This phenomenon is connected to the concept jamming
which suggests the generality of an idea that one can take polymer glasses through solid-to-liquid transition by thermalization
through temperature
or by a load.It is expected within the jamming picture that we could process polymers at lower temperature or even at room temperature.
高分子链低温流动去拥挤转变高分子加工玻璃化转变
Unjamming transitionCold flowPolymer processingGlass transition
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