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1. 重庆工商大学机械工程学院废油资源化技术与装备教育部工程研究中心,重庆,400067
2. 四川大学高分子科学与工程学院高分子材料工程国家重点实验室 成都 610065>
纸质出版日期:2012-2-20,
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袁毅, 张贤明, 崔爽, 申开智. 复合应力场剪切诱导成型PP-R自增强管材的结构与性能研究[J]. 高分子学报, 2012,(2):194-198.
YUAN Yi, ZHANG Xianming, CUI Shuang, SHEN Kaizhi. STRUCTURE AND PROPERTIES OF TWO-DIMENSIONAL SELF-REINFORCED PP-R PIPES EXTRUDED BY USING SHEARING-DRAWING COMPOUND STRESS FIELD DIE[J]. Acta Polymerica Sinica, 2012,(2):194-198.
袁毅, 张贤明, 崔爽, 申开智. 复合应力场剪切诱导成型PP-R自增强管材的结构与性能研究[J]. 高分子学报, 2012,(2):194-198. DOI: 10.3724/SP.J.1105.2012.11139.
YUAN Yi, ZHANG Xianming, CUI Shuang, SHEN Kaizhi. STRUCTURE AND PROPERTIES OF TWO-DIMENSIONAL SELF-REINFORCED PP-R PIPES EXTRUDED BY USING SHEARING-DRAWING COMPOUND STRESS FIELD DIE[J]. Acta Polymerica Sinica, 2012,(2):194-198. DOI: 10.3724/SP.J.1105.2012.11139.
利用自行设计制造的剪切拉伸双向复合应力场挤管装置生产出了双向自增强的无规共聚聚丙烯(PP-R C180)管材
研究分析了该双向应力场的剪切诱导效应对PP-R C180管材的结晶熔融、取向和拉伸强度的影响.结果表明
剪切拉伸双向复合应力场的引入所带来的剪切诱导效应促进了PP-R C180分子有序性的增加
使PP-R C180体系分子更容易形成分别沿管材周向和轴向方向的取向
因而保持甚至提高了耐热性与结晶速率
降低了结晶度
改变了PP-R C180的结晶结构与形态
诱导出了全新的晶
进而改善了管材的强度性能.与常规管材相比
自增强管材在保持其熔点不降低的前提下
使结晶度从常规管材的44.96%降至40.03%
降低了4.93%;轴向强度从常规管材的23.35 MPa最高增强到25.49 MPa
提高了9.2%;周向强度从常规管材的22.71 MPa最高增强到26.54 MPa
提高了16.9%
且增强之后管材的周向强度已经高于了轴向强度
更优化地配置了聚合物材料的性能
更充分地满足了受内压管材使用的现实需求.
By using a shearing-drawing two-dimensional compound stress field die developed by the authors
two-dimensional self-reinforcement polypropylene random copolymer(PP-R C180) pipes were extruded.The tensile strength
molecule orientation and crystal melting were studied.The results indicate that the molecule degree of order is improved by shear-inducement of shearing-drawing two-dimensional compound stress field.The orientation of molecule is easier along the circular and axial directions of PP-R C180 pipes respectively.The heat resistance and crystallization velocity are kept
and even improved.The degree of crystallinity is reduced.The self-reinforced PP-R C180 pipes show different crystallization structure and morphology.-phase is induced in the self-reinforced pipes.The tensile strength is improved too.The crystallinity decreases from 44.96% of conventional pipes to 40.03% of self-reinforced pipes.The best axial tensile strength of self-reinforced pipes is 25.49 MPa
but that of the conventional pipes' is 23.35 MPa. And that the circular tensile strength increases from 22.71 MPa of conventional pipes to 26.54 MPa of self-reinforced pipes at the most and the improvement is 16.9%.At the same time
the melting point of self-reinforced pipes is kept
even higher than that of the conventional pipes'.Moreover
the circular tensile strength of self-reinforced pipes is higher than the axial tensile strength and it rather satisfies the requirement of pipes.
剪切拉伸双向复合应力场剪切诱导双向自增强无规共聚聚丙烯
Shearing-drawing two-dimensional compound stress fieldShear-inducementTwo-dimensional self-reinforcementPP-R
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