Xu-zheng Sha, Yu-lian Pang, Ying-quan Zou. SYNTHESIS AND IMAGING APPLICATIONS OF THE ACTIVE ETHER COMPOUNDS OF PYROGALLOL POLYCONDENSATION DIVINYLBENZENE RESIN[J]. Acta Polymerica Sinica, 2012,(12):1448-1458.
A kind of active ether compound with acetal structure was synthesized through the adding-reaction between ethyl vinyl ether and pyrogallol polycondensation resins.The optimized reaction conditions are as follows:35℃
the mixture of methylene chloride and acetone (50∶50) as the solvent
sulfamic acid as the catalyst
the molar ratio of vinyl ether to phenolic hydroxyl group being 3∶1
reacting for 14 h.This kind of active ether compound can be used in room temperature chemically amplified positive photosensitive imaging and positive thermal imaging as an inhibitational/accelerational reagent for being able to be acid-decomposed and heat-decomposed under room temperature.Being used in CTP thermal imaging directions
it makes for the plates high sensitivity
anti-alkaline and high stability.Being used in positive CTcP photosensitive imaging directions
it makes for the plates excellent performance of integrated imaging.Being used in positive photoresist imaging directions
it makes for the positive photoresist high sensitivity and high resolution.
关键词
活性醚化物阻溶促溶剂阳图热敏CTP版阳图CTcP版正性抗蚀剂
Keywords
Active ether compoundsInhibitational/accelerational reagentsPositive thermal CTP platesPositive CTcP platesPositive photoresist