Xin-can Xu, Shun-hua Zhang. STUDY ON THE STRENGTH AND DYEING PROPERTIES OF UHMWPE FIBERS BY ADBD PLASMA TREATMENT[J]. Acta Polymerica Sinica, 2013,(12):1520-1524.
Xin-can Xu, Shun-hua Zhang. STUDY ON THE STRENGTH AND DYEING PROPERTIES OF UHMWPE FIBERS BY ADBD PLASMA TREATMENT[J]. Acta Polymerica Sinica, 2013,(12):1520-1524. DOI: 10.3724/SP.J.1105.2013.13113.
采用介质阻挡放电(ADBD)等离子体发生装置,以不同的工艺对UHMWPE纤维进行表面改性,并用分散染料对改性前后的纤维进行染色,研究了改性纤维的表面形貌、化学结构、染色性能及强度.结果表明,改性后UHMWPE纤维表面出现了大量刻蚀凹坑,表面粗糙度增加;FTIR分析发现,处理纤维表面出现了CO、C=O、OH等含氧极性基团,改善了纤维表面的化学极性;等离子体处理对UHMWPE纤维的强度影响较大,处理功率过高或时间过长,会使纤维的强度大幅度地下降,在处理功率为60~90 W,时间为45 s以内,纤维强度损失在10%以内;经等离子体处理,纤维的染色性能得到改善,纤维的K/S值从0.902提高到了1.625;综合考虑实验的最佳工艺参数为27 s、80 W.
Abstract
Ultra-high molecular weight polyethylene (UHMWPE) fibers were modified by an air dielectric barrier discharge (ADBD) plasma generating device to improve the dyeing properties.The treatment process was carried out with various operating parameters such as input power and treatment time.Then the treated and untreated fibers were dyed with disperse dye to study the treatment effect.Surface topography
chemical construction
tensile strength and dyeing properties of the modified fibers were studied.It was found that the surface roughness of the fibers was improved by plasma etching which was confirmed by scanning electron microscopy (SEM) results.Fourier transform infrared spectroscopy (FTIR) analysis revealed a significant increase of oxygen-based functional groups (CO
C=O
OH
etc.) on the surfaces of UHMWPE fibers
which indicated that the chemical polarity of the modified fibers was improved after ADBD plasma treatment.Meanwhile
the plasma treatment had a strong effect on the strength of UHMWPE fibers
the strength showed a very drastic decrease at high input power and long treatment time.When the input power was 60~90 W and treatment time was less than 45 s
the strength loss was generally less than 10%.Moreover
the dyeing properties of the fibers were improved after plasma treatment
the K/S values of the fibers increased from 0.902 to 1.625
and the optimum processing parameters were 27 s and 80 W.