In order to improve mechanical properties of the foams made by acrylated epoxidized soybean oil (AESO)
AESO was further modified with maleic anhydride (MA) to yield another polymerizable resin (MA-AESO) in this work.Accordingly
more double bonds were attached to triglycerides of the soybean oil.Then
the MA-AESO resin was copolymerized with diluent monomer styrene (St) to produce biodegradable MA-AESO foams.Meanwhile
cell structure and compressive properties of the foams prepared at different ratios of MA-AESO/St and curing conditions were characterized.In addition
biodegradability of the forms was investigated by soil burial test.It was found that the foams had higher compressive property than AESO foams
because the former contained more double bonds in triglycerides of the soybean oil
which increased cross-linking density of the foams.Thus
environmental-friendly foams with mechanical performance comparable to traditional petroleum based stiff unsaturated polyester foam plastics can be obtained even at high proportions of the vegetable oil component.In spite of having high cross-linking density
weight loss due to soil burial biodegradation of MA-AESO foams was higher than that of AESO foams
which may be related to the increased amount of ester groups in MA-AESO molecules.
关键词
环氧大豆油马来酸和丙烯酸双重改性泡沫塑料力学性能生物降解
Keywords
Epoxidized soybean oilModification with maleic anhydride and acrylic acidPlastic foamMechanical propertiesBiodegradability