Rheological Behavior of Biomimetic Rubber

Shao-yong Huang; Xiao-lei Xu; Feng Ye; Quan Chen

doi:10.11777/j.issn1000-3304.2023.23213

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Rheological Behavior of Biomimetic Rubber

Research Article | 更新时间：2024-02-08

- Rheological Behavior of Biomimetic Rubber
- Acta Polymerica Sinica Vol. 55, Issue 3, Pages: 359-368(2024)
- 作者机构：
  
  高分子物理与化学国家重点实验室中国科学院长春应用化学研究所长春 130022
- 作者简介：
  
  Xiao-lei Xu, E-mail: xlxu@ciac.ac.cnFeng Ye
  Feng Ye, E-mail: yefeng@ciac.ac.cn
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2023.23213
  CLC：
- Published：20 March 2024，
  
  Published Online：15 January 2024，
  
  Received：23 October 2023，
  
  Accepted：15 November 2023
扫描看全文
黄绍永, 徐晓雷, 叶峰, 陈全. 仿生天然橡胶生胶的流变行为表征. 高分子学报, 2024, 55(3), 359-368

Huang, S. Y.; Xu, X. L.; Ye, F.; Chen, Q. Rheological behavior of biomimetic rubber. Acta Polymerica Sinica, 2024, 55(3), 359-368
黄绍永, 徐晓雷, 叶峰, 陈全. 仿生天然橡胶生胶的流变行为表征. 高分子学报, 2024, 55(3), 359-368 DOI： 10.11777/j.issn1000-3304.2023.23213.

Huang, S. Y.; Xu, X. L.; Ye, F.; Chen, Q. Rheological behavior of biomimetic rubber. Acta Polymerica Sinica, 2024, 55(3), 359-368 DOI： 10.11777/j.issn1000-3304.2023.23213.

摘要

明确橡胶的流变行为对于理解其链结构和加工行为，以及二者之间的关系至关重要. 本文中通过流变学测试手段对比研究了仿生天然橡胶和天然橡胶的生胶的线性黏弹行为和非线性流变行为. 相比于商品化合成异戊橡胶，文中的仿生天然橡胶和天然橡胶表现出更为相近的线性黏弹行为，主要表现为近乎相同的平台模量、末端弛豫时间、复数黏度，以及在加工窗口区域相同的剪切黏度对剪切速率的依赖性. 非线性松弛行为的结果表明，天然橡胶和仿生天然橡胶的松弛模量对于时间均表现为幂律关系，对时间和应变的依赖具有可分离性，二者的衰减函数对应变的依赖性由于链结构和微观精细结构的不同而存在一定差异.

Abstract

关键词

仿生天然橡胶天然橡胶线性黏弹性衰减函数

Keywords

Biomimetic rubberNatural rubberLinear viscoelasticityDamping function

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Key Laboratory of Rubber-Plastics, Ministry of Education, Qingdao University of Science & Technology

华南理工大学机械与汽车工程学院

材料科学与工程学院　广州 510640South China University of Technology, Guangzhou 510640 School of Materials Science and Engineering

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Callege of Materials Science and Engineering, Beijing Engineering Research Center of Advanced Elastomers, Key Laboratory of Carbon Fiber and Functional Polymer, Ministry of Education, Beijing University of Chemical Technology

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