Construction of Stretchable Conductive Fibers Based on Polypyrrole and Their Application in Electrothermal Therapy

Yi-meng Li; Wen-xin Li; Xiao-li Liu; Li-qin Tang; Sha-sha Wang; Fu-jun Wang; Lu Wang; Ji-fu Mao

doi:10.11777/j.issn1000-3304.2023.23214

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Construction of Stretchable Conductive Fibers Based on Polypyrrole and Their Application in Electrothermal Therapy

Research Article | 更新时间：2024-02-08

- Construction of Stretchable Conductive Fibers Based on Polypyrrole and Their Application in Electrothermal Therapy
- Acta Polymerica Sinica Vol. 55, Issue 3, Pages: 309-319(2024)
- 作者机构：
  
  东华大学纺织学院纺织面料技术教育部重点实验室纺织行业生物医用纺织材料与技术重点实验室上海市现代纺织前沿科学研究基地上海 201620
- 作者简介：
  
  Ji-fu Mao, E-mail: jifu.mao@dhu.edu.cn
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2023.23214
  CLC：
- Published：20 March 2024，
  
  Published Online：06 December 2023，
  
  Received：26 August 2023，
  
  Accepted：10 October 2023
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李沂蒙, 李雯昕, 刘晓莉, 唐丽琴, 王莎莎, 王富军, 王璐, 毛吉富. 聚吡咯基本征可拉伸导电纤维构建及电热理疗应用. 高分子学报, 2024, 55(3), 309-319

Li, Y. M.; Li, W. X.; Liu, X. L.; Tang, L. Q.; Wang, S. S.; Wang, F. J.; Wang, L.; Mao, J. F. Construction of stretchable conductive fibers based on polypyrrole and their application in electrothermal therapy. Acta Polymerica Sinica, 2024, 55(3), 309-319
李沂蒙, 李雯昕, 刘晓莉, 唐丽琴, 王莎莎, 王富军, 王璐, 毛吉富. 聚吡咯基本征可拉伸导电纤维构建及电热理疗应用. 高分子学报, 2024, 55(3), 309-319 DOI： 10.11777/j.issn1000-3304.2023.23214.

Li, Y. M.; Li, W. X.; Liu, X. L.; Tang, L. Q.; Wang, S. S.; Wang, F. J.; Wang, L.; Mao, J. F. Construction of stretchable conductive fibers based on polypyrrole and their application in electrothermal therapy. Acta Polymerica Sinica, 2024, 55(3), 309-319 DOI： 10.11777/j.issn1000-3304.2023.23214.

摘要

为解决现有可拉伸电极存在的制备工艺复杂和本征可拉伸性能差的问题，采用简单的原位聚合方法，通过优化掺杂剂，开发了一种具有本征可拉伸性的聚吡咯基导电纤维. 在导电纤维的制备过程中，磺基水杨酸钠被用作掺杂剂和增塑剂，使得导电纤维展现出出色的初始电导率(6.34 S/cm)，并且在100%拉伸应变下仍保持5.37 S/cm的良好导电性能. 此外，基于弹性导电纤维的加热器具有优秀的焦耳热性能. 当施加5 V电压时，其表面温度可达到60 ℃，为热疗提供了可靠的加热效果. 进一步将导电纤维集成到电热手套中，实验发现在手指关节运动过程中，手套表面温度仅下降了4.89%，可实现对运动关节的稳定热疗. 这为雷诺综合征和关节损伤疼痛等疾病的物理治疗提供了便捷有效的实施方案.

Abstract

To solve the problems of complicated preparation process and poor intrinsic stretchability of existing stretchable electrodes

this study employs a simple

in situ

polymerization method and optimizes the dopant to develop a conducting polypyrrole-based fiber with excellent intrinsic stretchability. Sodium salicylate is utilized as both a dopant and a plasticizer during the fabrication process

resulting in a highly conductive fiber with an initial conductivity of 6.34 S/cm

which remains at 5.37 S/cm even under 100% strain. Furthermore

the elastic conductive fiber-based heater exhibits excellent Joule heating performance. When a 5 V voltage is applied

the surface temperature can reach 60 ℃

providing reliable heating effects for thermotherapy. Moreover

when integrating the conductive fibers into electric heating gloves

experimental results show that the surface temperature of the gloves only decreases by 4.89% during finger joint movements

enabling stable thermotherapy for moving joints. This provides a convenient and effective implementation for the physical treatment of conditions such as Raynaud's syndrome and joint injury pain.

关键词

聚吡咯导电纤维本征可拉伸焦耳热热疗

Keywords

PolypyrroleConductive fiberIntrinsically stretchableJoule heatThermotherapy

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College of Textile, Key Laboratory of Textile Science & Technology of the Ministry of Education, Key Laboratory of Biomedical Textile Materials and Technology in Textile Industry, Donghua University

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