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Opto-Electric-Magnetic Coupling Properties of Tetrathiafulvalene- Pyromelliticdiimide Organic Cocrystals
- Acta Polymerica Sinica Vol. 55, Issue 3, Pages: 320-327(2024)
- 作者机构：
1.包头稀土研究院 白云鄂博稀土资源研究与综合利用全国重点实验室 包头 014030
2.浙江大学光电科学与工程学院 极端光学技术与仪器全国重点实验室 杭州 310027
- 作者简介：
Bei-bei Xu, E-mail: bbxu2019@zju.edu.cn
- 基金信息：
DOI：10.11777/j.issn1000-3304.2023.23240
CLC：Published：20 March 2024，
Published Online：16 January 2024，
Received：01 October 2023，
Accepted：15 November 2023
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窦青青, 李子成, 满涛, 许贝贝. 四硫富瓦烯-苯均四酸二亚酰胺有机共晶的光电磁耦合特性. 高分子学报, 2024, 55(3), 320-327
Dou, Q. Q.; Li, Z. C.; Man, T.; Xu, B. B. Opto-electric-magnetic coupling properties of tetrathiafulvalene-pyromelliticdiimide organic cocrystals. Acta Polymerica Sinica, 2024, 55(3), 320-327
窦青青, 李子成, 满涛, 许贝贝. 四硫富瓦烯-苯均四酸二亚酰胺有机共晶的光电磁耦合特性. 高分子学报, 2024, 55(3), 320-327 DOI： 10.11777/j.issn1000-3304.2023.23240.
Dou, Q. Q.; Li, Z. C.; Man, T.; Xu, B. B. Opto-electric-magnetic coupling properties of tetrathiafulvalene-pyromelliticdiimide organic cocrystals. Acta Polymerica Sinica, 2024, 55(3), 320-327 DOI： 10.11777/j.issn1000-3304.2023.23240.
摘要
利用四硫富瓦烯(TTF)给体和苯均四酸二亚酰胺(PMDI)受体，发展了一种新型有机共晶TTF-PMDI. 该共晶给受体分子间具有强电荷转移作用，并表现出铁电性和磁电耦合效应，包括磁电容效应和磁场诱导铁电极化的变化，光刺激下，该共晶还表现出电容和铁电极化变化，详细讨论了这些效应产生的机制，并探讨了三线态电荷转移态对电容和铁电极化变化的影响. 本文的研究结果将促进多功能共晶的材料和器件的发展，为多场感知领域的应用提供了一种新的可能.
Abstract
The rapid development of intelligent robots raises increasing demand of multifunctional sensing materials and devices. However
most of currently developed materials only have two-field coupling effect. They lack multi-modal sensing ability. This article proposes a new strategy to develop multi-field coupling materials through the control of inter-molecular charge transfer interaction. Here
centimeter long organic co-crystal tetrathiafulvalene (TTF)-pyromelliticdiimide (PMDI) with opto-electric-magnetic coupling effect is developed by saturated precipitation method. It has room-temperature ferroelectric effect with a remnant polarization of 4 µC/cm
2
. It also shows room-temperature magneto-electric coupling effect
including magnetic field-induced capacitance change of 1.5×10
-3
%/Oe and ferroelectric polarization change with magneto-electric coupling coefficient of 1.18 nC/(cm
2
·Oe). Moreover
this effect can be controlled by light stimuli. It is demonstrated that the relatively weaker inter-molecular charge transfer interaction than that of intra-molecular interaction makes the co-crystal more vulnerable to external stimuli than single component crystal. In addition
the intersystem crossing between singlet and triplet charge transfer state also induces magnetic-field effect and influences the electric dipoles related capacitance and polarization. All these factors lead to the generation of multiple freedom to tune the opto-electric-magnetic properties of the co-crystal. The results of this study will promote the development of multifunctional cocrystal materials and devices
and promote their applications for multifunctional sensing.
关键词
有机共晶光电磁耦合多场传感
Keywords
Organic cocrystalOpto-electric-magneto couplingMulti-field sensing
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