Preparation and Study of Lignin-based Composite Films with Photothermal-Engergy Generation and Photothermal-antibacterial Performances

Yuan-long Guo; Tong-hui Xu; He-bang Li; Xiao-qin Long; Hai-bo Xie

doi:10.11777/j.issn1000-3304.2023.23286

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Preparation and Study of Lignin-based Composite Films with Photothermal-Engergy Generation and Photothermal-antibacterial Performances

更新时间：2024-04-24

- Preparation and Study of Lignin-based Composite Films with Photothermal-Engergy Generation and Photothermal-antibacterial Performances
- Acta Polymerica Sinica Pages: 1-12(2024)
- 作者机构：
  
  贵州大学材料与冶金学院高分子材料与工程系贵阳 550025
- 作者简介：
  
  Hai-bo Xie, E-mail: hbxie@gzu.edu.cn
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2023.23286
  CLC：
- Published Online：24 April 2024，
  
  Received：18 December 2023，
  
  Accepted：30 January 2024
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郭元龙, 徐同辉, 李合邦, 龙晓琴, 谢海波. 具有光热-发电及光热-抗菌效应的木质素基复合膜的制备与研究. 高分子学报, doi: 10.11777/j.issn1000-3304.2023.23286

Guo, Y. L.; Xu, T. H.; Li, H. B.; Long, X. Q.; Xie, H. B. Preparation and study of lignin-based composite films with photothermal-engergy generation and photothermal-antibacterial performances. Acta Polymerica Sinica, doi: 10.11777/j.issn1000-3304.2023.23286
郭元龙, 徐同辉, 李合邦, 龙晓琴, 谢海波. 具有光热-发电及光热-抗菌效应的木质素基复合膜的制备与研究. 高分子学报, doi: 10.11777/j.issn1000-3304.2023.23286 DOI：

Guo, Y. L.; Xu, T. H.; Li, H. B.; Long, X. Q.; Xie, H. B. Preparation and study of lignin-based composite films with photothermal-engergy generation and photothermal-antibacterial performances. Acta Polymerica Sinica, doi: 10.11777/j.issn1000-3304.2023.23286 DOI：

摘要

利用具有优异光热性能的木质素磺酸钠(LSS)为原料，与具有局域表面等离子体共振效应的金纳米粒子(Au NPs)通过原位共混策略制备出具有协同光热效应的LSS/PVA@Au复合膜材料. 在复合膜中，LSS的结构上的功能基团对Au

起到分散、稳定、螯合和还原作用. Au NPs的引入使得LSS50/PVA50@Au1复合膜的表面更加粗糙，平均粗糙度为30.3 nm，但是在紫外到近红外区具有更强更宽的吸收谱带. LSS含量的提高有助于材料光热性能的增强，LSS50/PVA50复合膜的最高温度可升至(120.6±3.1) ℃. 利用Au NPs的协同光热效应，LSS50/PVA50@Au1复合膜的温度最高可以达到(190.1±3.5) ℃，光热转换效率为42.47%. 不仅如此，该复合膜材料也具有光热-发电效应，利用TEG可以将吸收的热量转换为电能，在5个太阳光照射下LSS50/PVA50@Au1产生的电压最高为(280.8±4.6) mV，电流为(48.9±1.9) mA. 而由于对近红外光(NIR)良好的光响应性，该复合膜同样具有良好的抗菌性能，在1.47 W/cm

NIR照射10 min后，对大肠杆菌和金黄色葡萄球菌的杀菌率可以达到99.5%和99.2%. 本研究利用具有

共轭结构的LSS与具有LSPR效应的Au NPs相结合，通过原位共混策略制备出LSS/PVA@Au复合材料可以将储量丰富的、高效、清洁、绿色的太阳能资源转化为可以利用储存的电能，同时该材料也具有光热-抗菌的效果.

Abstract

Sodium lignosulfonate (LSS) with good photothermal property and gold nanoparticles (Au NPs) with excellent localized surface plasmon resonance (LSS) were used as raw materials to fabricate LSS/PVA@Au composite films with synergistic photothermal effect through

in situ

blending strategy. During the preparation process

the functional groups on the LSS structure play an important role in dispersing

stabilizing

chelating and reducing Au

. The existence of Au NPs makes the surface of the LSS/PVA@Au composite film rougher

with an average roughness of 30.3 nm

which also endows its stronger and wider absorption in the ultraviolet to near infrared region. The increase of LSS content is beneficial to the enhancement of photothermal property of the LSS/PVA composite material. The maximum temperature of the LSS50/PVA50 composite film can reach (120.6±3.1) ℃ with thermal conversion efficiency of 27.61% under standard 5 sun irradiation. Benefiting from the synergistic photothermal effect of Au NPs

the highest temperature of (190.1±3.5) ℃ can be attained for LSS50/PVA50@Au1 composite film with thermal conversion efficiency of 42.47%. A thermoelectric generator are powered by LSS50/PVA50 and LSS50/PVA50@Au1 composite films successfully

which can convert the heat absorbed into electric energy. The maximum voltage generated by LSS50/PVA50@Au1 is (280.8±4.6) mV and the corresponding current is (48.9±1.9) mA under standard 5 sun irradiation. Due to the good photo-responsiveness to near infrared light (NIR)

the LSS50/PVA50@Au1 composite film also show satisfactory photothermal antibacterial performance. After 10 min irradiation of 1.47 W NIR

the antibacterial rates of

E.coil

and

S.aureus

can reach 99.5% and 99.2%

respectively. In summary

through a simple

green

and efficient composite blending strategy

abundant solar energy resources can be utilized effectively through the synergistic photothermal effect of LSS and Au NPs. Considering the satisfactory eﬀective antibacterial activity of the LSS50/PVA50@Au1 composite

this work may provide perspectives on the design of green photothermal antibacterial materials

via

pulp and paper industry waste lignin sulfonate as well as contributes to the enrichment of linin structure and chemistry.

关键词

木质素磺酸钠纳米金粒子光热效应光热抗菌

Keywords

Sodium lignin sulfonateGold nanoparticlesPhotothermal effectPhotothermal-antibacterial

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