Dual <italic style="font-style: italic">in situ</italic> Synthesis of Ultra-low Filled Calcium Borate/Polyethylene Terephthalate Nanocomposites for Excellent Capacitive Properities

Fei-yan Luo; Yan-tong Li; Li He; Jia-yu Zhang; Jia-le Li; Nan-sun; Quan-ping Zhang

doi:10.11777/j.issn1000-3304.2024.24014

您当前的位置：

首页 >

文章列表页 >

Dual in situ Synthesis of Ultra-low Filled Calcium Borate/Polyethylene Terephthalate Nanocomposites for Excellent Capacitive Properities

更新时间：2024-04-23

- Dual in situ Synthesis of Ultra-low Filled Calcium Borate/Polyethylene Terephthalate Nanocomposites for Excellent Capacitive Properities
- Acta Polymerica Sinica Pages: 1-9(2024)
- 作者机构：
  
  西南科技大学环境友好能源材料国家重点实验室材料与化学学院绵阳 621010
- 作者简介：
  
  Quan-ping Zhang, E-mail: zhangqp@swust.edu.cn
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2024.24014
  CLC：
- Published Online：19 April 2024，
  
  Received：15 January 2024，
  
  Accepted：17 February 2024
扫描看全文
罗非艳, 李岩潼, 何利, 张迦宇, 李佳乐, 孙囡, 张全平. 双原位合成超低填充硼酸钙/聚对苯二甲酸乙二醇酯纳米复合材料及其介电储能研究. 高分子学报, doi: 10.11777/j.issn1000-3304.2024.24014

Luo, F. Y.; Li, Y. T.; He, L.; Zhang, J. Y.; Li, J. L; Sun, N.; Zhang, Q. P. Dual in situ synthesis of ultra-low filled calcium borate/polyethylene terephthalate nanocomposites for excellent capacitive properities. Acta Polymerica Sinica, doi: 10.11777/j.issn1000-3304.2024.24014
罗非艳, 李岩潼, 何利, 张迦宇, 李佳乐, 孙囡, 张全平. 双原位合成超低填充硼酸钙/聚对苯二甲酸乙二醇酯纳米复合材料及其介电储能研究. 高分子学报, doi: 10.11777/j.issn1000-3304.2024.24014 DOI：

Luo, F. Y.; Li, Y. T.; He, L.; Zhang, J. Y.; Li, J. L; Sun, N.; Zhang, Q. P. Dual in situ synthesis of ultra-low filled calcium borate/polyethylene terephthalate nanocomposites for excellent capacitive properities. Acta Polymerica Sinica, doi: 10.11777/j.issn1000-3304.2024.24014 DOI：

摘要

引入超低含量纳米粒子至聚合物基体能够同时改善介电常数和击穿强度，从而显著提升聚合物薄膜电容储能密度，有助于器件小型化. 目前溶液共混策略中的有机溶剂回收及环境安全等诸多因素限制了超低填充聚合物纳米复合材料规模化制备及应用. 本文工作提出双原位合成策略：聚对苯二甲酸乙二醇酯(PET)聚合与硼酸钙纳米粒子生长同步，无需任何溶剂实现0.2 wt%硼酸钙纳米粒子均匀分散于PET基体，且界面良好相容. 聚酯纳米复合材料介电常数为4.91，最大储能密度为10.69 J/cm

，是纯PET 1.94倍. 这种双原位合成策略能潜在扩展其他聚酯纳米复合体系，且能批量化制备，为探索聚酯纳米复合材料电能存储和其他应用提供理论依据.

Abstract

Incorporating ultra-low loading of nanoparticles into polymer matrices can simultaneously improve the dielectric constant and breakdown strength

thereby significantly increasing the capacitance energy storage density of polymer nanocomposites and miniaturing electronics and devices. However

there are still a series of tough issues to be dealt with

such as the use of organic solvents in the current solution blending

which face enormous challenges in scalable preparation and application of the polymer nanocomposites. Here

a dual

in situ

synthesis strategy is proposed

namely the polymerization of polyethylene terephthalate (PET) synchronizes with the growth of calcium borate nanoparticles. In particular

0.2 wt% calcium borate nanoparticles are uniformly dispersed in the PET matrix without any solvent

and rich compatibility of the interfaces occurs. The dielectric constant reaches 4.91 and the maximum energy storage density is up to 10.69 J/cm

which is 1.94 times that of neat PET. The unique dual

in situ

synthesis strategy tends to be extended to the scalable fabrication of polyester nanocomposites filled with a variety of borates

which paves a way for exploring electrical energy storage and other applications of polyester nanocomposites.

关键词

双原位超低填充介电性能储能密度

Keywords

Dual in situUltra-low filledDielectric propertiesEnergy storage density

references

Feng Q. K.; Zhong S. L.; Pei J. Y.; Zhao Y.; Zhang D. L.; Liu D. F.; Zhang Y. X.; Dang Z. M. Recent progress and future prospects on all-organic polymer dielectrics for energy storage capacitors. Chem. Rev., 2022, 122(3), 3820-3878. doi:10.1021/acs.chemrev.1c00793http://dx.doi.org/10.1021/acs.chemrev.1c00793

Chen Q.; Shen Y.; Zhang S. H.; Zhang Q. M. Polymer-based dielectrics with high energy storage density. Annu. Rev. Mater. Res., 2015, 45, 433-458. doi:10.1146/annurev-matsci-070214-021017http://dx.doi.org/10.1146/annurev-matsci-070214-021017

胡静文, 段广宇, 胡祖明, 于俊荣, 王彦, 诸静. 改性钛酸钡/聚间苯二甲酰间苯二胺复合薄膜的制备与介电性能. 高分子材料科学与工程, 2021, 37(5), 50-59.

成桑, 李雨抒, 梁家杰, 李琦. 介电高分子及其纳米复合材料的电容储能应用. 高分子学报, 2020, 51(5), 469-483. doi:10.11777/j.issn1000-3304.2020.20001http://dx.doi.org/10.11777/j.issn1000-3304.2020.20001

钟少龙, 郑明胜, 邢照亮, 陈新, 黄河, 张翔宇, 许振波, 党智敏. 无机颗粒形状对高储能密度有机复合材料介电性能的影响. 复合材料学报, 2020, 37(11), 2760-2768. doi:10.13801/j.cnki.fhclxb.20200728.001http://dx.doi.org/10.13801/j.cnki.fhclxb.20200728.001

Zhang T. D.; Sun H.; Yin C.; Jung Y. H.; Min S.; Zhang Y.; Zhang C. H.; Chen Q. G.; Lee K. J.; Chi Q. G. Recent progress in polymer dielectric energy storage: from film fabrication and modification to capacitor performance and application. Prog. Mater. Sci., 2023, 140, 101207. doi:10.1016/j.pmatsci.2023.101207http://dx.doi.org/10.1016/j.pmatsci.2023.101207

Wu X. D.; Chen X.; Zhang Q. M.; Tan D. Q. Advanced dielectric polymers for energy storage. Energy Storage Mater., 2022, 44, 29-47. doi:10.1016/j.ensm.2021.10.010http://dx.doi.org/10.1016/j.ensm.2021.10.010

Luo H.; Wang F.; Guo R.; Zhang D.; He G. H.; Chen S.; Wang Q. Progress on polymer dielectrics for electrostatic capacitors application. Adv. Sci., 2022, 9(29), 2202438. doi:10.1002/advs.202202438http://dx.doi.org/10.1002/advs.202202438

赵宇霄, 冯鑫, 冯晨曦, 王玉辉, 程金雪, 于晓亮, 郭敏杰. 微/纳米多孔低介电聚酰亚胺薄膜的研究进展. 高分子材料科学与工程, 2023, 39(5), 173-181.

Yang M. Z.; Guo M. F.; Xu E. X.; Ren W. B.; Wang D. Y.; Li S. A.; Zhang S. J.; Nan C. W.; Shen Y. Polymer nanocomposite dielectrics for capacitive energy storage. Nat. Nanotechnol., 2024, Doi: 10.1038/s41565-023-01541-w.http://dx.doi.org/10.1038/s41565-023-01541-w.

Zhang X.; Chen W. W.; Wang J. J.; Shen Y.; Gu L.; Lin Y. H.; Nan C. W. Hierarchical interfaces induce high dielectric permittivity in nanocomposites containing TiO2@BaTiO3 nanofibers. Nanoscale, 2014, 6(12), 6701-6709. doi:10.1039/c4nr00703dhttp://dx.doi.org/10.1039/c4nr00703d

张全平, 陈瑞超, 杜芳艳, 刘修, 李银涛, 杨文彬, 周元林. 高填充钛酸钡/氟硅橡胶纳米复合材料制备及介电性能调控. 高分子材料科学与工程, 2022, 38(2), 17-23.

张慧, 衡婷婷, 房正刚, 胡欣, 方亮, 陆春华. 高储能陶瓷/聚偏氟乙烯复合电介质的研究进展. 复合材料学报, 2021, 38(7), 2107-2122. doi:10.13801/j.cnki.fhclxb.20201030.002http://dx.doi.org/10.13801/j.cnki.fhclxb.20201030.002

Hao Y. N.; Wang X. H.; Bi K.; Zhang J. M.; Huang Y. H.; Wu L. W.; Zhao P. Y.; Xu K.; Lei M.; Li L. T. Significantly enhanced energy storage performance promoted by ultimate sized ferroelectric BaTiO3 fillers in nanocomposite films. Nano Energy, 2017, 31, 49-56. doi:10.1016/j.nanoen.2016.11.008http://dx.doi.org/10.1016/j.nanoen.2016.11.008

Shen Z. H.; Wang J. J.; Zhang X.; Lin Y. H.; Nan C. W.; Chen L. Q.; Shen Y. Space charge effects on the dielectric response of polymer nanocomposites. Appl. Phys. Lett., 2017, 111(9), 092901. doi:10.1063/1.4991079http://dx.doi.org/10.1063/1.4991079

Thakur Y.; Zhang T.; Iacob C.; Yang T. N.; Bernholc J.; Chen L. Q.; Runt J.; Zhang Q. M. Enhancement of the dielectric response in polymer nanocomposites with low dielectric constant fillers. Nanoscale, 2017, 9(31), 10992-10997. doi:10.1039/c7nr01932ghttp://dx.doi.org/10.1039/c7nr01932g

Zhang T.; Chen X.; Thakur Y.; Lu B.; Zhang Q. Y.; Runt J.; Zhang Q. M. A highly scalable dielectric metamaterial with superior capacitor performance over a broad temperature. Sci. Adv., 2020, 6(4), eaax6622. doi:10.1126/sciadv.aax6622http://dx.doi.org/10.1126/sciadv.aax6622

Che J. J.; Zakri C.; Ly I.; Neri W.; Laurichesse E.; Chapel J. P.; Poulin P.; Yuan J. K. High-energy-density waterborne dielectrics from polyelectrolyte-colloid complexes. Adv. Funct. Mater., 2023, 33(26), 2213804. doi:10.1002/adfm.202213804http://dx.doi.org/10.1002/adfm.202213804

Li L.; Cheng J. S.; Cheng Y. Y.; Han T.; Liu Y.; Zhou Y.; Zhao G. H.; Zhao Y.; Xiong C. X.; Dong L. J.; Wang Q. Significant improvements in dielectric constant and energy density of ferroelectric polymer nanocomposites enabled by ultralow contents of nanofillers. Adv. Mater., 2021, 33(35), 2102392. doi:10.1002/adma.202102392http://dx.doi.org/10.1002/adma.202102392

Luo H.; Zhou X. F.; Ellingford C.; Zhang Y.; Chen S.; Zhou K. C.; Zhang D.; Bowen C. R.; Wan C. Y. Interface design for high energy density polymer nanocomposites. Chem. Soc. Rev., 2019, 48(16), 4424-4465. doi:10.1039/c9cs00043ghttp://dx.doi.org/10.1039/c9cs00043g

Feng Y.; Li W. L.; Hou Y. F.; Yu Y.; Cao W. P.; Zhang T. D.; Fei W. D. Enhanced dielectric properties of PVDF-HFP/BaTiO3-nanowire composites induced by interfacial polarization and wire-shape. J. Mater. Chem. C, 2015, 3(6), 1250-1260. doi:10.1039/c4tc02183ehttp://dx.doi.org/10.1039/c4tc02183e

Shen Z. H.; Wang J. J.; Lin Y. H.; Nan C. W.; Chen L. Q.; Shen Y. High-throughput phase-field design of high-energy-density polymer nanocomposites. Adv. Mater., 2018, 30(2), 1704380. doi:10.1002/adma.201704380http://dx.doi.org/10.1002/adma.201704380

Cacciari M.; Mazzanti G.; Montanari G. C. Weibull statistics in short-term dielectric breakdown of thin polyethylene films. IEEE Trans. Dielectr. Electr. Insul., 1994, 1(1), 153-159. doi:10.1109/94.300243http://dx.doi.org/10.1109/94.300243

Eaton, G. R. NMR of boron compounds. J. Chem. Educ., 1969, 46(9), 547. doi:10.1021/ed046p547http://dx.doi.org/10.1021/ed046p547

Bull S. D.; Davidson M. G.; van den Elsen J. M. H.; Fossey J. S.; Jenkins A. T. A.; Jiang Y. B.; Kubo Y. J.; Marken F.; Sakurai K.; Zhao J. Z.; James T. D. Exploiting the reversible covalent bonding of boronic acids: recognition, sensing, and assembly. Acc. Chem. Res., 2013, 46(2), 312-326. doi:10.1021/ar300130whttp://dx.doi.org/10.1021/ar300130w

Hubert A. J.; Hargitay B.; Dale J. The structure and relative stabilities of boric esters of 1,2- and 1,3-diols. J. Chem. Soc., 1961, 931. doi:10.1039/jr9610000931http://dx.doi.org/10.1039/jr9610000931

Bai C.; Wu Z. J.; Ye X. S.; Liu H. N.; Liu Z.; Zhang H. F.; Li Q.; Li J.; Wang X. M. Influence of the pH in reactions of boric acid/borax with simple hydroxyl compounds: investigation by Raman spectroscopy and DFT calculations. ChemistrySelect, 2019, 4(48), 14132-14139. doi:10.1002/slct.201903740http://dx.doi.org/10.1002/slct.201903740

Applegarth L. M. S. G. A.; Pye C. C.; Cox J. S.; Tremaine P. R. Raman spectroscopic and ab initio investigation of aqueous boric acid, borate, and polyborate speciation from25 to 80 ℃. Ind. Eng. Chem. Res ., 2017, 56(47), 13983-13996. doi:10.1021/acs.iecr.7b03316http://dx.doi.org/10.1021/acs.iecr.7b03316

Brooks W. L. A.; Sumerlin B. S. Synthesis and applications of boronic acid-containing polymers: from materials to medicine. Chem. Rev., 2016, 116(3), 1375-1397. doi:10.1021/acs.chemrev.5b00300http://dx.doi.org/10.1021/acs.chemrev.5b00300

柏春, 刘海宁, 刘忠, 叶秀深, 张慧芳, 李军, 吴志坚. 硼酸/硼砂与多羟基化合物在水溶液中的反应: pH、电导率、Raman光谱研究. 盐湖研究, 2020, 28(2), 56-64.

陈经涛. 硼酸与多羟基醇反应机理研究. 中国西部科技(学术), 2007, 6(11), 1-2.

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

High Field Dielectric Properties of Silk Fibroin Films

Polymer Dielectrics and Their Nanocomposites for Capacitive Energy Storage Applications

Electromagnetic Properties of Polypyrrol-Co0.7Cu0.1Zn0.2Fe2O4 Nanocomposites Prepared by in situ Polymerization

Progress on Graphene/Polymer Nanocomposites with Superior Dielectric Properties

Related Author

Xing-yi Huang

Ping-kai Jiang

Ying-ke Zhu

Jie Chen

Si-qi Wang

Yu-shu Li

Qi Li

Jia-jie Liang

Related Institution

Shanghai Key Laboratory of Electrical Insulation and Thermal Ageing, Shanghai Jiao Tong University

State Key Laboratory of Power System, Department of Electrical Engineering, Tsinghua University

School of Materials Science and Engineering, Shenyang University of Technology

Department of Polymer Science and Engineering, School of Chemistry and Biological Engineering, University of Science and Technology Beijing

Postal code：100190
Tel：010-62588927 Email：gfzxb@iccas.ac.cn
Technical support is provided by Beijing Founder electronics co., LTD 京ICP备05002797号-8 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰

Dual in situ Synthesis of Ultra-low Filled Calcium Borate/Polyethylene Terephthalate Nanocomposites for Excellent Capacitive Properities

DOI：10.11777/j.issn1000-3304.2024.24014

摘要

Abstract

关键词

Keywords

references