Research Progress on Preparing Fluoropolymers <italic style="font-style: italic">via</italic> Reversible Deactivation Radical Polymerization

Shan-tao Han; Meng-li Xu; Mao Chen

doi:10.11777/j.issn1000-3304.2024.24017

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Research Progress on Preparing Fluoropolymers via Reversible Deactivation Radical Polymerization

更新时间：2024-04-18

- Research Progress on Preparing Fluoropolymers via Reversible Deactivation Radical Polymerization
- Acta Polymerica Sinica Pages: 1-15(2024)
- 作者机构：
  
  复旦大学高分子科学系聚合物分子工程国家重点实验室上海 200433
- 作者简介：
- 基金信息：
- DOI：10.11777/j.issn1000-3304.2024.24017
  CLC：
- Published Online：18 April 2024，
  
  Received：17 January 2024，
  
  Accepted：06 February 2024
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韩善涛, 许梦丽, 陈茂. 可逆失活自由基聚合制备含氟聚合物的研究进展. 高分子学报, doi: 10.11777/j.issn1000-3304.2024.24017

Han, S. T.; Xu, M. L.; Chen, M. Research progress on preparing fluoropolymers via reversible deactivation radical polymerization. Acta Polymerica Sinica, doi: 10.11777/j.issn1000-3304.2024.24017
韩善涛, 许梦丽, 陈茂. 可逆失活自由基聚合制备含氟聚合物的研究进展. 高分子学报, doi: 10.11777/j.issn1000-3304.2024.24017 DOI：

Han, S. T.; Xu, M. L.; Chen, M. Research progress on preparing fluoropolymers via reversible deactivation radical polymerization. Acta Polymerica Sinica, doi: 10.11777/j.issn1000-3304.2024.24017 DOI：

摘要

含氟聚合物具有许多优异的理化性能，在化工、新能源、生物医药等领域取得重要应用. 可逆失活自由基聚合反应(RDRP)是实现聚合物精准合成的重要手段. 然而，含氟烯烃单体的RDRP报道相对较少. 本综述对侧链含氟聚合物和主链含氟聚合物的可控合成进展进行介绍，简述了含氟丙烯酸酯、含氟苯乙烯、三氟氯乙烯、四氟乙烯、偏氟乙烯、六氟丙烯、全氟烯基醚等单体的RDRP案例，总结了该领域面临的挑战. 鉴于众多前沿领域对定制化合成含氟聚合物提出了迫切需求，发展含氟聚合物的可控合成方法将有助于拓宽含氟聚合物范围，推动开发高性能含氟聚合物材料.

Abstract

Fluoropolymers possess many outstanding physical and chemical properties

allowing applications in aerospace

defense

chemicals

new energy

biomedicine

etc

. Reversible deactivation radical polymerization (RDRP) is among the important methods for realizing precise synthesis of polymers. However

compared with the (methyl)acrylate and styrene derivatives

RDRPs of fluorinated monomers are very limited. Recently

a growing number of research reports demonstrated that the precise regulation of polymer structures contributes to improving properties of polymers

promoting the development of high-end materials. Herein

this review focuses on RDRPs of fluorinated monomers

introduces the research advancements of the controlled synthesis of side-chain and main-chain fluorinated polymers

and summarizes the RDRP reports of fluorinated acrylates

fluorinated styrene

chlorotrifluoroethylene

tetrafluoroethylene

vinylidene fluoride

hexafluoropropylene

and perfluoroalkyl vinyl ethers. Given the urgent need for customized synthesis of fluorinated polymers in many frontier fields

the development of controlled synthesis methods for fluorinated polymers will not only contribute to regulating the structural scope of fluorinated polymers but also facilitate the production of high-performance fluorinated polymer materials. This review serves as a valuable resource for researchers working in the field of fluorinated polymers

providing an overview of the current state of the art and briefly illustrating the prospects and challenges for the RDRP of fluorinated monomers.

关键词

含氟聚合物含氟烯烃可控失活自由基聚合活性聚合

Keywords

FluoropolymersFluoroalkenesReversible deactivation radical polymerization (RDRP)Living polymerization

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Xin-hua Wan

Xin-ming Pu

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Qi-jing Chen

Ze-sheng An

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Beijing National Laboratory for Molecular Sciences, Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, Department of College of Chemistry and Molecular Engineering, Peking University

State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University

Institute of Nanochemistry and Nanobiology, Shanghai University

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Research Progress on Preparing Fluoropolymers via Reversible Deactivation Radical Polymerization

DOI：10.11777/j.issn1000-3304.2024.24017

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