LI Bin, CHEN Wenguang, WANG Xiaogong, ZHOU Qixiang. PREPARATION AND SURFACE MORPHOLOGY OF PNIPAAm-GRAFTED LAYERS ON POLYPROPYLENE FILMS[J]. Acta Polymerica Sinica, 2002,(6):780-785.
LI Bin, CHEN Wenguang, WANG Xiaogong, ZHOU Qixiang. PREPARATION AND SURFACE MORPHOLOGY OF PNIPAAm-GRAFTED LAYERS ON POLYPROPYLENE FILMS[J]. Acta Polymerica Sinica, 2002,(6):780-785.DOI:
N-Isopropylacrylamide (NIPAAm) was introduced onto the surface of polypropylene (PP) films to form a layer of poly(N-isopropylacrylamide) (PNIPAAm) by UV-induced surface photograft polymerization reaction.Improvement on UV intensity and reaction temperature favored the increase of the grafting yield
yet it went through a maximum as monomer concentration was increased.Two photograft techniques
the xanthen-9-one pre-dipping method and dormant radical method
were tried and higher grafting yields were achieved by the latter.The existence of PNIPAAm grafted polymer layer was confirmed by FTIR
ESCA and SEM measurements.The acrylamide band Ⅰand Ⅱ in FTIR spectra of the grafted polymer shifted as the temperature changed
which revealed the temperature sensitivity of the grafted films.Moreover
a special sphere-like surface morphology of the NIPAAm layers due to the temperature-responsive behaviors was observed by SEM.