浏览全部资源
扫码关注微信
纸质出版日期:2003-12-20,
扫 描 看 全 文
翟媛萍, 章维一, 侯丽雅. 一种用于快速成型工艺的红光光敏树脂的性能研究[J]. 高分子学报, 2003,(6):883-886.
ZHAI Yuanping, ZHANG Weiyi, HOU Liya. STUDIES ON RED-LIGHT PHOTOSENSITIVE RESIN USED IN RAPID PROTOTYPING[J]. Acta Polymerica Sinica, 2003,(6):883-886.
合成了一种吸收波长为 680nm的菁染料-有机硼盐复合物光引发剂CDBC
以 680nm激光二极管发射的激光作为光源
研究了由CDBC、EA612、POTMPTA组成的红光光敏树脂在快速成型工艺中的应用
考察了影响树脂几个主要性能即粘度、光固化速度、体积收缩率的因素 .结果表明
EA612含量高
POTMPTA含量低
树脂粘度大
体积收缩率小 ;相反
EA612含量低
POTMPTA含量高
则树脂粘度低
体积收缩率大 ;光引发剂CDBC含量 5%以内时对树脂粘度和体积收缩率没有影响
CDBC含量增加
树脂的表固速度加快
但当CDBC含量大于3%时
表固速度基本不变 .预聚物EA612质量分数 70%
单体POTMPTA质量分数 27%
光引发剂CDBC质量分数3%时
树脂粘度为420mPa·s
表固时间为 1.0s
固化体积收缩率为 4.0%
具有较好的综合性能.
A photoinitiator
cyanine dye-borate complex(CDBC)
sensitive to light of 680 nm was synthesized
and the factors affecting the viscosity
the curing time and the volumetric shrinkage ratio of resins
composed of CDBC
EA612 and POTMPTA were also studied.The experimental results showed that a high weight content of EA612 and a low weight content of POTMPTA resulted in high viscosity and low volumetric shrinkage ratio of the resin
and vice versa.The curing time of the resin decreased with the increasing of the weight content of CDBC
when the weight content of CDBC was not more than 3%.However.the curing time of resin did not decrease with the increasing of the weight content of CDBC
when the weight content of CDBC is more than 3%. When the weight content of CDBC was not more than 5%
the viscosity and the volumetric shrinkage ratio of resin had no relationship with the weight content of CDBC. When the weight contents of EA612
POTMPTA and CDBC were 70%
27% and 3%
respectively
the viscosity of the resin was 420 mPa·s
the curing time of the resin was 1.0 s
the volumetric shrinkage ratio of the resin was 4.0% and the cured resin exhibited good properties.
立体光造型激光二极管光敏树脂固化机理树脂性能
0
浏览量
10
下载量
2
CSCD
关联资源
相关文章
相关作者
相关机构