注册 登录 English Version 中国高分子学术平台
研究简报 | 更新时间:2021-03-19
    • 发蓝光材料聚烷基芴的合成和性能研究

    • SYNTHESIS OF POLY(9,9-DIHEXYLFLUORENE) BLUE-LIGHT EMITTING MATERIALS AND ITS PROPERTIES

    • 刘承美

      ,  

      薛锋

      ,  

      黄树槐

      ,  
    • 高分子学报   2003年第5期 页码:734-737
    • 纸质出版日期:2003-10-20

    扫 描 看 全 文

  • 引用本文

    阅读全文PDF

  • 刘承美, 薛锋, 黄树槐. 发蓝光材料聚烷基芴的合成和性能研究[J]. 高分子学报, 2003,(5):734-737. DOI:

    LIU Chengmei, XUE Feng, HUANG Shuhuai. SYNTHESIS OF POLY(9,9-DIHEXYLFLUORENE) BLUE-LIGHT EMITTING MATERIALS AND ITS PROPERTIES[J]. Acta Polymerica Sinica, 2003,(5):734-737. DOI:

  •  
  •  
    论文导航

    摘要

    Abstract

    A soluble blue-light emitting polymer,Poly(9,9-dihexylfluorene),was prepared by using the oxidative polymerization method.The monomer,9,9-dihexylfluorene,was prepared in a DMSO/benzene mixture with solid KOH as catalyst and the product was purified by chromatography with ethyl ether/n-hexane (5/95) as the eluant.Poly(9,9-dihexylfluorene) was synthesized by chemical polymerization utilizing FeCl3 as an oxidizing agent under argon atmosphere at room temperature for three days.Its structure and properties were characterized by FTIR,1H-NMR,TGA,GPC,UV-Vis and photoluminescence spectra. The experimental results showed that the molecular weight of the polymer measured with GPC was Mw/Mn=27692/24476. The thermal degradation temperature (weight loss 5%) of the polymer was over 400℃ either in air,or in Ar.The polymer was found to be fusible at high temperature and soluble in most common organic solvents,such as chloroform,tetrahydrofuran and dichlomethane. Both in solution and film state,the polymer shows strong fluorescent excitation characteristics.The peak wavelength of its photoluminescence in chloroform solution was around 420 nm excited at 320 nm.The polymer can be processed as film by a solution-casting method and shows unique blue light emitting properties,and may be widely used in electronuminescent devices as blue-light emitting diodes and polymer lasers.

    关键词

    聚烷基芴; 合成; 性能

    Keywords

    更多指标>

    0

    浏览量

    8

    下载量

    4

    CSCD

    文章被引用时,请邮件提醒。
    提交
    工具集
    下载
    参考文献导出
    分享
    收藏
    添加至我的专辑

    相关文章

    一种含三苯胺链段的PPV类交替共聚物的合成、表征及性能
    主链含冠醚的聚对亚苯基亚乙烯基类发光共聚物的合成与性能研究
    双官能团液体脂环族环氧化合物的合成与性能
    一种基于联苯二甲酸为介晶基元的含磷液晶共聚酯的合成与表征
    邻菲罗啉聚西佛碱金属配合物的合成及磁性能研究

    相关作者

    暂无数据

    相关机构

    四川大学化学学院 环保型高分子材料国家地方联合工程实验室 环境友好高分子材料教育部工程研究中心
    扬州大学化学化工学院
    扬州大学测试中心
    0