ZENG You, WANG Ruichun, ZHOU Benlian. MECHANICAL SENSITIVITY OF MACROPOROUS POLY(VINYL FORMAL) HYDROGELS TO WATER CONTENT[J]. Acta Polymerica Sinica, 2005,(3):363-367.
ZENG You, WANG Ruichun, ZHOU Benlian. MECHANICAL SENSITIVITY OF MACROPOROUS POLY(VINYL FORMAL) HYDROGELS TO WATER CONTENT[J]. Acta Polymerica Sinica, 2005,(3):363-367.DOI:
Smart hydrogels have been applied widely as sensors and actuators in many fields
such as artificial muscles
drug control release
fluid control and so on However
their further applications have been hindered by the slow respond rate and the critical surrounding medium.A macroporous nonionie poly(vinyl formal) hydrogel (PVFM) sensitive to water content
was synthesized by adding pore-forming agent.It showed a satisfied swelling/deswelling rate with the change in water content due to the presence of interconnecting pores.The swelling pressure of this hydrogel in water may reach its maximum within 80s.and the deswelling pressure of the swollen hydrogel may decrease to 5% of its initial value within 4 h in the process of air-drying.Comparing with the conventional dense hydrogel
the maeroporous PVFM showed many different behaviors
the volume did not decrease with the loss of water
but a phenomenon of volume recovery occurred during the air-drying process.On the other hand
the compressive modulus of the macropomus hydrogel did not increase monotonously with the decrease of water content as that of conventional hydrogels did
but decreased about 47% at the initial stage of drying process This abnormal behavior is mainly related to the load-bearing modes of macroporous gels is with different water contents.The rapid response of macropomus gels is attributed to the weaker interaction between polymer and water
the higber porosity and the elasticity recovery of network.Since the maemporous PVFM hydmgels show the rapid swelling/deswelling rate and the satisfied sensitivity of mechanical properties to water content
they have the large potentialities to be used as sensors and actuators in flow eontrol.humidity control and so on.