WANG Wei, LIU Lianying, HUANG Zhenhua, YANG Wantai. STUDY ON PHOTOINITIATED DISPERSION POLYMERIZATION OF ACRYLAMIDE BY USING POLY(ACRYLIC ACID)-graft-NONYLPHENOXYPOLY (ETHYLENE OXIDE) AS THE DISPERSANT[J]. Acta Polymerica Sinica, 2005,(3):320-326.
WANG Wei, LIU Lianying, HUANG Zhenhua, YANG Wantai. STUDY ON PHOTOINITIATED DISPERSION POLYMERIZATION OF ACRYLAMIDE BY USING POLY(ACRYLIC ACID)-graft-NONYLPHENOXYPOLY (ETHYLENE OXIDE) AS THE DISPERSANT[J]. Acta Polymerica Sinica, 2005,(3):320-326.DOI:
Photoinitiated dispersion polymerization of acrylamide (AM) has been carried out in the media of aqueous tert-butyl alcohol (TBA) (TBA=50 vol%~80 vol%)
using poly (acrylic acid)-graft-nonylphenoxypoly-(ethylene oxide)(PAA-g-NPEO) as a dispersant and 2
2-dimethoxy-2-phenylacetophenone as initiator.The evolution of the dispersion polymerization indicated that there was no induction period and a 90% conversion could be obtained in 40 min.Influences of various parameters
such as medium polarity
monomer concentration
initiator concentration
dispersant concentration
incident light intensity
reaction temperature and layer thickness on molecular weight and particle size were investigated Polymers of high molecular weight
up to 6.5×106 were obtained According to the observation of TEM
most of the polymer particles clustered together or scattered with a unifoml size as in a typical dispersion polymerization system.