WU Nian, GAO Baojiao, XU Li, LI Yanbin. STUDY ON STRUCTURE AND PROPERTIES OF ACRYLAMIDE COPOLYMER P(AM-co-NaAMPS) OF STRONG ANION TYPE[J]. Acta Polymerica Sinica, 2004,(3):355-360.
WU Nian, GAO Baojiao, XU Li, LI Yanbin. STUDY ON STRUCTURE AND PROPERTIES OF ACRYLAMIDE COPOLYMER P(AM-co-NaAMPS) OF STRONG ANION TYPE[J]. Acta Polymerica Sinica, 2004,(3):355-360.DOI:
The copolymefization of aerylamide (AM) and sodium 2-acrylamido-2-methyl-propane-sulfonate (NaAMPS) was carried in aqueous solution
and a series of copolymer P(AM-co-NaAMPS) with varied composition were prepared The structure and composition of the copolymers were characterized by FTIR spectroscopy and element analysis.The viscosities of the copolymers were determined using an Ubbelohde viscometer
and the intrinsic viscosities by which molecular weight can be calculated were determined with the method of extiapolation to zeio concentration At the same time the Huggins constants by which the interaction between polymer and solvent can be displayed were also obtained.The apparent viscosities of aqueous solutions and brine of the copolymers were measured using a low shear rotational viscometer.Thermal stability experiments were carried out formeasufing the maintaining ratios of viscosity at high temperatures.In this work
the relationships between the structare and composition and the properties of the copolymers P(AM-co-NaAMPS) were studied.The experimental result shows that the properties of the copolymers P(AM-co-NaAMPS) depend strongly on their structure and compositions
and incorporation of the NaAMPS segments in polymer backbone of PAM results in excellent properties of the copolymers
such as better solubility
better thickening ability
improved resistance to temperature and improved salt tolerance due to the strong anionic property of sulfonate groups and sterlc hindrance of great side groups.These properties are significant in enhanced oil recovery.The molecular weisat of the copolymers is influenced by their composition and the polymerization process At the same time
the molecular weight is also an important parameter influencing the properties of the eopolymer.The experimental results indicate that the properties of the copolymer vary regularly with its structure and composition.