WAN Junmin, HU Zhiwen, CHEN Wenxing, CHEN Haixiang, YU Zhicheng. SYNTHESIS AND APPLICATION ON ENRICHMENT OF METAL IONSOF CELLULOSE FIBRE GRAFTED β-CYCLODEXTRIN[J]. Acta Polymerica Sinica, 2004,(4):566-572.
WAN Junmin, HU Zhiwen, CHEN Wenxing, CHEN Haixiang, YU Zhicheng. SYNTHESIS AND APPLICATION ON ENRICHMENT OF METAL IONSOF CELLULOSE FIBRE GRAFTED β-CYCLODEXTRIN[J]. Acta Polymerica Sinica, 2004,(4):566-572.DOI:
A new kind of functional cellulose fibre grafted β-cyclodextrin (β-CD) with epichlorohydrin was synthesized in alkaline solution.The fibre not only kept the original characterization of β-CD to form inclusion complexes
but also contained more hydroxyl group(—OH) with could coordinate to inorganic heavy metal ions. The effects of factors such as temperature
concentration of solution
pH value
etc. on the enrichment properties were investigated. The results showed that the process of isothermal enrichment fits the Langmuir equation.The enrichment velocity is controlled by liquid film diffusion.The enrichment capabilitie of the fibre for inorganic heavy metal ions (Pb2+
Cu2+
Cd2+) were investigated and the enrichment contents of fiber for the above-mentioned metal ions were 0.25