QIAN Zhenyu, GUO Baohua, XU Jun, LIU Ping. KINETIC MODEL OF CHAIN EXTENSION REACTION OF NYLON 1010 AND ANALYSIS OF EXPERIMENTAL RESULTS[J]. Acta Polymerica Sinica, 2004,(4):511-517.
QIAN Zhenyu, GUO Baohua, XU Jun, LIU Ping. KINETIC MODEL OF CHAIN EXTENSION REACTION OF NYLON 1010 AND ANALYSIS OF EXPERIMENTAL RESULTS[J]. Acta Polymerica Sinica, 2004,(4):511-517.DOI:
The kinetic model of chain extension reaction between bisoxazoline and carboxyl group was founded and modified to fit the real experimental results. By the Runge-Kutta numerical method
not only has the change of reaction conversion with time been clearly revealed
but also the key factors that mainly influence the chain extension have been easily tested.The ideal linear model of chain extension accords to a large extent with the former period of the reaction. However
it cannot illustrate the “degradation” in the latter period due to the thermal unstability of products.Modified linear model gives more congruent results.During the whole period of the reaction
the reaction rate constant k and ratio of both reactants r are the key factors. The changes of reaction conditions
such as temperature and chain extender dosage
are simulated easily by varying the value of k and r.Considering the diffusibility in the polymer melt with high viscosity
the distinction of coupling effect of BOZ and PBO can be explained.No other than the same reason
the analysis could only be kept in the qualitative stage at present.