CHEN Zhiyan, LI Xiaodong, WANG Jun, WANG Ge. STUDY ON POLYFERROCARBOSILANE AS PRECURSOR OF MAGNETIC SILICON CARBIDE CERAMIC[J]. Acta Polymerica Sinica, 2005,(4):535-539.
CHEN Zhiyan, LI Xiaodong, WANG Jun, WANG Ge. STUDY ON POLYFERROCARBOSILANE AS PRECURSOR OF MAGNETIC SILICON CARBIDE CERAMIC[J]. Acta Polymerica Sinica, 2005,(4):535-539.DOI:
A polyferrocarbosilane(PFCS) was synthesized from low molecular weight polysilane and ferrecene.The synthesis techniques including reaction temperature
pyrolysis temperature and ferrocene content were investigated.The molecular weight and soft point of PFCS increase with raising reaction temperature
pyrolysis temperature
and adding more ferrocene.The most suitable synthesis conditions for PFCS ale as follows
reaction temperature 350-420℃.pyrolysis temperature 450~510℃.The reaction temperature and pyrolysis temperature decrease greatly because of adding ferrocene.PFCS was charactefized by element analysis
FT-IR and 1H-NMR.As a result
element iron was inducted to the polymer
and it seemed that the structure of PFCS is similar to that of colycarbosilane (PCS).The silicon carbide ceramic obtained from PFCS shows some magnetic properties.