LI Xiuyu, WU Wenhui, WANG Jianquan, QIAN Xiaolin. SWELLING BEHAVIOR OF TEMPERATURE-SENSITIVE HYDROGELS BASED ON P(NIPAM-co-ADMOAB) POLYMERS[J]. Acta Polymerica Sinica, 2005,(5):779-782.
LI Xiuyu, WU Wenhui, WANG Jianquan, QIAN Xiaolin. SWELLING BEHAVIOR OF TEMPERATURE-SENSITIVE HYDROGELS BASED ON P(NIPAM-co-ADMOAB) POLYMERS[J]. Acta Polymerica Sinica, 2005,(5):779-782.DOI:
A series of poly(N-isopropylacrylamide-co-methacryloyloxyethyl dimethyloctyl ammonium bromide) [P(NIPAM-co-ADMOAB)] hydrogels were prepared.Theinfluences of the amount of ADMOAB in eopolymefie gels on the swelling behavior were investigated.The deswelling and reswelling kinetics were also studied.Results showed that the equilibrium swelling ratios (ESRs) of copolymeric gels increased with the enhanced ADMOAB content in the composition at temperatures below LCST.and the maximum ESR was 126 compared with a value of 28 for homopolymefic gel P(NIPAM)
and the ESR for all copolymeric gels tended to zero independent of the composition when the temperature was above LCST The rate constants in deswelling process increased at first and then decreased with increasing the ADMOAB amount.and the final water retention for copolymeric gels(about1%) was much lower than that of P(NIPAM)(20%).The swelling ratios during resweUing process increased with the ADMOAB amount
andthe diffusion of waterinto P(NIPAM-co-ADMOAB) gels was found to be a non-Fiekianmode.Thorlsh decreased in saline solutions
swelling ratios for copolrmeric gels were not significantly influenced by ionic strength with NaCl concentration from 0.1 to 0.3 mol/L and higher than those of homopolymeric gels in deionized water with the same swelling time.P(NIPAM-co-ADMOAB) hydmgels can be expected as good candidates for controlled drug delivery systems and separation processes.