侧链含羟基聚(D,L-丙交酯-co-碳酸酯)的合成与表征

毛静; 郭颖志; 夏宇正; 顾忠伟

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侧链含羟基聚(D,L-丙交酯-co-碳酸酯)的合成与表征

研究简报 | 更新时间：2021-03-19

- 侧链含羟基聚(D,L-丙交酯-co-碳酸酯)的合成与表征
- SYNTHESIS AND CHARACTERIZATION OF POLY(D,L-LACTIDE-co-CYCLIC CARBONATE)S WITH HYDROXYL PENDANT FUNCTIONAL GROUPS
- 高分子学报 2006年第9期页码：1121-1124
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- 纸质出版日期：2006-12-20，
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毛静, 郭颖志, 夏宇正, 顾忠伟. 侧链含羟基聚(D,L-丙交酯-co-碳酸酯)的合成与表征[J]. 高分子学报, 2006,(9):1121-1124.

MAO Jing, GUO Yingzhi, XIA Yuzheng, GU Zhongwei. SYNTHESIS AND CHARACTERIZATION OF POLY(D,L-LACTIDE-co-CYCLIC CARBONATE)S WITH HYDROXYL PENDANT FUNCTIONAL GROUPS[J]. Acta Polymerica Sinica, 2006,(9):1121-1124.
毛静, 郭颖志, 夏宇正, 顾忠伟. 侧链含羟基聚(D,L-丙交酯-co-碳酸酯)的合成与表征[J]. 高分子学报, 2006,(9):1121-1124. DOI：

MAO Jing, GUO Yingzhi, XIA Yuzheng, GU Zhongwei. SYNTHESIS AND CHARACTERIZATION OF POLY(D,L-LACTIDE-co-CYCLIC CARBONATE)S WITH HYDROXYL PENDANT FUNCTIONAL GROUPS[J]. Acta Polymerica Sinica, 2006,(9):1121-1124. DOI：

摘要

Abstract

A six-member cyclic carbonate with protected functional groups was synthesized from tetramethylolmethane

benzaldehyde and ethyl choroformate．Coplymerization of D

L-lactide with cyclic carbonate was carried out throush conventional ring-opening polymerization using Sn(Oct)2 as the catalyst．The effects of different catalysts

polymerization time and monomer-to-catalyst molar ratio on the molecular weight were investigated．The methods of removing protected groups were studied．Results showed the protected groups were effectively removed via catalytic hydrogenation．Poly(D

L-lactide-co—cycliccarbonate)s with hydroxyl pendant functional groups was obtained．

关键词

聚（DL-丙交酯-co-碳酸酯）功能化生物材料

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