Linear low-density polyethylene(LLDPE) was melt blended with styrene-maleic anbydride copolymer (SMA)．The blending films were then immersed in pely(ethylene glycol)400(PEG400)at room temperature．The surface composition of the blend films was determined by Fourier transform infra-red spectroscopy coupled with an variable incidence angle attenuated total reflection accessory(ATR—FTIR)．It has been found that PEG400 was grafted onto the surface of the films via esterification with SMA．PEG immemion promoted enrichment of SMA onto the surface of the films．The water contact angle data show that grafting of PEG400 can greatly improve the hvdrophilicity of the PE surface．These experiments show that surface functionalization of polyethylene films by blending SMA and then surface grafting of PEG is a feasible process

which suggest a viable and simple route for PE surface modification via blending and grafting．