The AFM-tip-induced crystallization of poly(ethylene oxide)(PEO)melt droplets was studied.The melt droplets with the heght of 50~100 nm and the lateral size of 2~3 μm were obtained by melting the PEO ultrathin film on the mica surface.Forthe PEO samples with the number average molecular weights(Mn)ranged from 1.0×10 3 to 1.0×104g/mol
the lateral perturbation from the AFM tip with hard-tapping or nanoscratch mode could not induce the growth of the flat—on lamellae. By contrast
under AFM nanoindentation mode
the tip—induced crystallization occufred when a sufficiently high vertical tip force was applied to the melt droplets of PEO with Mn≥1.0×lO4g/mol.Moreover
the experimental results indicated that AFM-tip—induced crystallization with nanoindentation method had PEO molecular weight(viscosity)dependence.