自组装的氢氟酸掺杂的聚苯胺微/纳米管

邓俊英; 张志明; 于良民; 万梅香

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自组装的氢氟酸掺杂的聚苯胺微/纳米管

研究论文 | 更新时间：2021-03-19

- 自组装的氢氟酸掺杂的聚苯胺微/纳米管
- SELF-ASSEMBLED POLYANILINE MICRO/NANOTUBES DOPED WITH HYDROFLUORIC ACID
- 高分子学报 2007年第3期页码：277-281
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- 纸质出版日期：2007-3-10，
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邓俊英, 张志明, 于良民, 万梅香. 自组装的氢氟酸掺杂的聚苯胺微/纳米管[J]. 高分子学报, 2007,(3):277-281.

DENG Junying, ZHANG Zhiming, YU Liangmin, WAN Meixiang. SELF-ASSEMBLED POLYANILINE MICRO/NANOTUBES DOPED WITH HYDROFLUORIC ACID[J]. Acta Polymerica Sinica, 2007,(3):277-281.
邓俊英, 张志明, 于良民, 万梅香. 自组装的氢氟酸掺杂的聚苯胺微/纳米管[J]. 高分子学报, 2007,(3):277-281. DOI：

DENG Junying, ZHANG Zhiming, YU Liangmin, WAN Meixiang. SELF-ASSEMBLED POLYANILINE MICRO/NANOTUBES DOPED WITH HYDROFLUORIC ACID[J]. Acta Polymerica Sinica, 2007,(3):277-281. DOI：

摘要

以氢氟酸为掺杂剂

采用无模板法制得了高电导率（10-2～10-1S/cm）聚苯胺微/纳米管（d=85～420 nm）.当［HF］/［An］=0.5时所得微/纳米管的形成机率高达100%.发现微/纳米管的直径和电导率均随［HF］/［An］比例的增加而增加.FTIR

UV-Vis

XRD结构表征证明所得的聚苯胺微/纳米管为掺杂态.

Abstract

Self-assembled micro/nanotubes of polyaniline (PANI) with a high conductivity (10-2～10-1S/cm) were synthesized by a template-free method in the presence of hydrofluoric acid (HF) as the dopant.The formation probability of PANI-HF micro/nanotubes was nearly 100% when the molar ratio of ［HF］/［An］ was equal to 0.5.The SEM and TEM images revealed that the average diameter of the micro/nanotubes was about 85～420 nm.Besides

it was found that the diameter and conductivity of micro/nanotubes at room-temperature increase with the increase of ［HF］/［An］ ratios.The micro/nanotubes characterized by FTIR and UV-Visible absorption spectrums are identical to the emeraldine salt state of PANI.

关键词

聚苯胺氢氟酸微/纳米管自组装无模板法

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