YU Yan, LIU Pengtao, JIAN Xigao, ZHANG Yuanhong, HONG Dingyi, LI Yang. SYNTHESIS AND PROPERTIES OF TETRAPOLYAMIDES CONTAINING 4,4′-METHYLENEDIANILINE MOIETY[J]. Acta Polymerica Sinica, 2006,(2):340-344.
YU Yan, LIU Pengtao, JIAN Xigao, ZHANG Yuanhong, HONG Dingyi, LI Yang. SYNTHESIS AND PROPERTIES OF TETRAPOLYAMIDES CONTAINING 4,4′-METHYLENEDIANILINE MOIETY[J]. Acta Polymerica Sinica, 2006,(2):340-344.DOI:
4’-methylanedianiline(MDA)and p-phenylene diamine(PPD).The synthesized polyamides were charaeterized by FHR and 1H-NMR.The polymers exhibitedinherent viscosities of l.24~2.32 dL/g and some were soluble in several organic solvents such as N-methyl pyrrolidone
N
N—dimethylacetamide and N
N— dimethylformamide.when the three kinds of diamines were in proper ratios.These polymers had glass transition temperatures above 301℃ and 5% weight loss above 438℃ in nitrogen.Some polyamide films were prepared from their NMP solutions and had tensile strength of 64~72 MPa
elongation at break of 4.9%-8.1% and tensile modulus of 1.7~2.1 GPa.The results showed that these polyamides showed the combination of excellent thermal properties